Novel bromination method for anilines and anisoles using NH4Br/H2O2 in CH3COOH

…, P Srinivasu, SJ Kulkarni, KV Raghavan

Index: Krishna Mohan; Narender; Srinivasu; Kulkarni; Raghavan Synthetic Communications, 2004 , vol. 34, # 12 p. 2143 - 2152

Full Text: HTML

Citation Number: 44

Abstract

Abstract A simple, efficient, regioselective, environmentally safe, and economical method for the oxybromination of anilines and anisoles without catalyst is reported. The electrophilic substitution of bromine generated in situ from ammonium bromide as a bromine source and hydrogen peroxide as an oxidant for the first time.# IICT Communication No. 01/X/07.

 Related Synthetic Route
aminobenzonitrile Structure

1885-29-6

aminobenzonitrile

~50%

2-Amino-5-bromobenzonitrile Structure

39263-32-6

2-Amino-5-bromo...

2-Amino-3-bromobenzonitrile Structure

114344-60-4

2-Amino-3-bromo...

N,N-Dimethylaniline Structure

121-69-7

N,N-Dimethylaniline

~%

2-Bromo-N,N-dimethylaniline Structure

698-00-0

2-Bromo-N,N-dim...

4-Bromo-N,N-dimethylaniline Structure

586-77-6

4-Bromo-N,N-dim...

2,4-dibromo-N,N-dimethylaniline Structure

64230-27-9

2,4-dibromo-N,N...

3,4-Dimethoxybenzyl Alcohol Structure

93-03-8

3,4-Dimethoxybe...

~96%

(2-BROMO-4,5-DIMETHOXYPHENYL)METHANOL Structure

54370-00-2

(2-BROMO-4,5-DI...

2-Chloroaniline Structure

95-51-2

2-Chloroaniline

~%

2-Bromo-6-chloroaniline Structure

59772-49-5

2-Bromo-6-chlor...

4-Bromo-2-chloroaniline Structure

38762-41-3

4-Bromo-2-chlor...

1-Methoxynapthalene Structure

2216-69-5

1-Methoxynapthalene

~99%

1-Bromo-4-methoxynaphthalene Structure

5467-58-3

1-Bromo-4-metho...


Home | MSDS/SDS Database Search | Journals | Product Classification | Biologically Active Compounds | Selling Leads | About Us | Disclaimer

Copyright © 2024 ChemSrc All Rights Reserved