Layered Double Hydroxides??Supported Diisopropylamide: Synthesis, Characterization and Application in Organic Reactions

…, C Reddy, B Sreedhar, BM Choudary

Index: Kantam, M. Lakshmi; Ravindra; Reddy, Ch. Venkat; Sreedhar; Choudary Advanced Synthesis and Catalysis, 2006 , vol. 348, # 4-5 p. 569 - 578

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Citation Number: 40

Abstract

Abstract The layered double hydroxides-supported diisopropylamide (LDH-DA) catalyst is found to be an efficient and selective solid base for aldol, Knoevenagel, Henry, Michael, transesterification and epoxidation reactions under liquid phase conditions. LDH-DA is synthesized by the interaction of lithium diisopropylamide with LDH-NO 3 (as-synthesized) and calcined LDH-NO 3. The LDH-DA (Mg/Al, 3/1) and their precursors are well ...