Bulletin of the Chemical Society of Japan

The Photochemical Reaction of 1, 2-Naphthoquinones with Aldehydes. III. The Reactions with Aromatic Aldehydes and α, β-Unsaturated Aliphatic Aldehydes

A Takuwa

Index: Takuwa,A. Bulletin of the Chemical Society of Japan, 1977 , vol. 50, p. 2973 - 2981

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Citation Number: 5

Abstract

Photochemical reactions of 1, 2-naphthoquinone and the substituted derivatives with a variety of aldehydes in the liquid phase have been investigated. The reaction with saturated aliphatic aldehydes gives a mixture of 3-acyl-1, 2-naphthalenediol and 1, 2-naphthalenediol monoacyl esters. On the other hand, the irradiation of the benzene solution of a 1, 2- naphthoquinone derivative and an aromatic aldehyde gives, in general, 1, 2- ...