Chemical simulation of biogenesis of the 2, 4, 5-trihydroxyphenylalanine quinone cofactor of copper amine oxidases: Mechanistic distinctions point toward a unique …

S Mandal, Y Lee, MM Purdy…

Index: Gierer,J.; Imsgard,F. Acta Chemica Scandinavica, Series B: Organic Chemistry and Biochemistry, 1977 , vol. 31, p. 537 - 545

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Citation Number: 25

Abstract

... J. Am. Chem. Soc. ... In addition, the failure to witness chemical precedent for the C2 hydration step of TPQ biogenesis suggests that this step must be facilitated at the enzyme active site, possibly via electrophilic activation by the active-site copper. ...

98-29-3

4-tert-Butylcatechol

Copper (II)-mediated autoxidation of tert-butylresorcinols

[Ling, Ke-Qing; Lee, Younghee; Macikenas, Dainius; Protasiewicz, John D.; Sayre, Lawrence M. Journal of Organic Chemistry, 2003 , vol. 68, # 4 p. 1358 - 1366]

Copper-Promoted overall transformation of 4-tert-butylphenol...

[Rinaldi, Andrea C.; Ponticelli, Gustavo; Oliva, Stefania; Di Giulio, Antonio; Sanjust, Enrico Bioorganic and Medicinal Chemistry Letters, 2000 , vol. 10, # 9 p. 989 - 992]

Über Orceinfarbstoffe, XXIII1). Die Autoxydation des 4.6??Di...

[Musso,H.; Maassen,D. Justus Liebigs Annalen der Chemie, 1965 , vol. 689, p. 93 - 108]