Untersuchungen zum Mechanismus der Rhodium (I)-katalysierten Hydrogen-Transfer-Reaktion von sekundären Alkoholen auf Imine

HA Brune, J Unsin, R Hemmer, M Reichhardt

Index: Brune, Hans-Albert; Unsin, Josef; Hemmer, Reinhard; Reichhardt, Monika Journal of Organometallic Chemistry, 1989 , vol. 369, p. 335 - 342

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Abstract

The results of a series of systematically performed experiments form the basis for a model that elucidates the catalytic cycle of the hydrogen transfer reaction from 2-propanol to imines forming secondary amines in the presence of Wilkinson's catalyst. ... Aus den Ergebnissen einer Reihe systematisch angelegter Experimente wird ein Modell über den Katalyse-Zyklus für die Hydrogen-Transfer-Reaktion von 2-Propanol auf Imine zu sekundären Aminen unter ...

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