Bulletin of the Chemical Society of Japan

Perkin-Markovnikov type reaction initiated with electrogenerated superoxide ion.

F Ojima, T Osa

Index: Ojima; Osa Bulletin of the Chemical Society of Japan, 1989 , vol. 62, # 10 p. 3187 - 3194

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Citation Number: 3

Abstract

The cyclic condensation of active methylene compounds such as diethyl malonate, dimethyl malonate, ethyl acetoacetate, or acetylacetone and dibromoalkanes such as 1, 2- dibromoethane, 1, 3-dibromopropane, 1, 4-dibromobutane, 1, 5-dibromopentane, 1, 6- dibromohexane, 1, 3-dibromobutane, or 1, 4-dibromopentane with electrogenerated superoxide ion was studied electrochemically in N, N-dimethylformamide (DMF) using ...