e.g. Filippa Pettersson or Cancer Res. 75(6) , 1102-12, (2015) or 10.1002/anie.201600521

Raney Ni–Al alloy-mediated reduction of benzils in water

…, HY Zhao, L Dai, T Thiemann, H Tashiro…

Index: Liu, Guo-Bin; Zhao, Hong-Yun; Dai, Lu; Thiemann, Thies; Tashiro, Hideki; Tashiro, Masashi Journal of Chemical Research, 2009 , # 9 p. 579 - 581

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Citation Number: 3

Abstract

Raney Ni–Al alloy in a dilute aqueous alkaline solution has been shown to be a powerful reducing agent and is highly effective for the reduction of alkylbenzils and alkoxybenzils to afford the corresponding 1, 2-diarylethers at 90° C, in the absence of organic solvents. 4, 4'- Dinitrobenzil was transformed selectively to 1, 2-bis (4-aminophenyl)-ethane.

1,4-Dibenzoylbutane Structure

1,4-Dibenzoylbutane

~50%

1-cyclohexyl-6-phenylhexane Structure

1-cyclohexyl-6-...

Benzene,1,1'-(1,6-hexanediyl)bis- Structure

Benzene,1,1'-(1...

1,6-Dicyclohexylhexane Structure

1,6-Dicyclohexy...

1,2-Bis(4-nitrophenyl)-1,2-ethanedione Structure

1,2-Bis(4-nitro...

~84%

4,4'-Ethylenedianiline Structure

4,4'-Ethylenedi...

1,2-bis(2-methylphenyl)ethane-1,2-dione Structure

1,2-bis(2-methy...

~87%

Benzene,1,1'-(1,2-ethanediyl)bis[2-methyl- Structure

Benzene,1,1'-(1...

1,3-Diphenylpropane-1,3-dione Structure

1,3-Diphenylpro...

~51%

Dibenzylmethane Structure

Dibenzylmethane

N/A Structure

Cyclohexane,1,1'-(1,3-propanediyl)bis- Structure

Cyclohexane,1,1...

1,2-DIBENZOYLETHANE Structure

1,2-DIBENZOYLETHANE

~51%

1,4-Diphenylbutane Structure

1,4-Diphenylbutane

4-cyclohexylbutylcyclohexane Structure

4-cyclohexylbut...

1-cyclohexyl-4-phenylbutane Structure

1-cyclohexyl-4-...

Benzil Structure

~22%

Benzene,(2-cyclohexylethyl)- Structure

Benzene,(2-cycl...

Cyclohexane,1,1'-(1,2-ethanediyl)bis- Structure

Cyclohexane,1,1...

Bibenzyl Structure

Ethanedione, bis(2-bromophenyl)- Structure

Ethanedione, bi...

~20%

Benzene,(2-cyclohexylethyl)- Structure

Benzene,(2-cycl...

Cyclohexane,1,1'-(1,2-ethanediyl)bis- Structure

Cyclohexane,1,1...

Bibenzyl Structure

1,2-Bis(4-fluorophenyl)-1,2-ethanedione Structure

1,2-Bis(4-fluor...

~26%

Benzene,(2-cyclohexylethyl)- Structure

Benzene,(2-cycl...

Cyclohexane,1,1'-(1,2-ethanediyl)bis- Structure

Cyclohexane,1,1...

Bibenzyl Structure

1,2-Ethanedione,1,2-bis(2-chlorophenyl)- Structure

1,2-Ethanedione...

~23%

Benzene,(2-cyclohexylethyl)- Structure

Benzene,(2-cycl...

Cyclohexane,1,1'-(1,2-ethanediyl)bis- Structure

Cyclohexane,1,1...

Bibenzyl Structure

4,4'-Dichloro benzil Structure

4,4'-Dichloro benzil

~22%

Benzene,(2-cyclohexylethyl)- Structure

Benzene,(2-cycl...

Cyclohexane,1,1'-(1,2-ethanediyl)bis- Structure

Cyclohexane,1,1...

Bibenzyl Structure

1,3-Dibenzoylpropane Structure

1,3-Dibenzoylpropane

~21%

1-cyclohexyl-5-phenylpentane Structure

1-cyclohexyl-5-...

5-phenylpentylbenzene Structure

5-phenylpentylb...

1,1'-(1,5-Pentanediyl)biscyclohexane Structure

1,1'-(1,5-Penta...

Benzil Structure

~54%

Benzene,(2-cyclohexylethyl)- Structure

Benzene,(2-cycl...

Cyclohexane,1,1'-(1,2-ethanediyl)bis- Structure

Cyclohexane,1,1...

Bibenzyl Structure

Ethanedione, bis(2-bromophenyl)- Structure

Ethanedione, bi...

~45%

Benzene,(2-cyclohexylethyl)- Structure

Benzene,(2-cycl...

Cyclohexane,1,1'-(1,2-ethanediyl)bis- Structure

Cyclohexane,1,1...

Bibenzyl Structure

1,2-Bis(4-fluorophenyl)-1,2-ethanedione Structure

1,2-Bis(4-fluor...

~46%

Benzene,(2-cyclohexylethyl)- Structure

Benzene,(2-cycl...

Cyclohexane,1,1'-(1,2-ethanediyl)bis- Structure

Cyclohexane,1,1...

Bibenzyl Structure

1,2-Ethanedione,1,2-bis(2-chlorophenyl)- Structure

1,2-Ethanedione...

~50%

Benzene,(2-cyclohexylethyl)- Structure

Benzene,(2-cycl...

Cyclohexane,1,1'-(1,2-ethanediyl)bis- Structure

Cyclohexane,1,1...

Bibenzyl Structure

4,4'-dibromobenzil Structure

4,4'-dibromobenzil

~51%

Benzene,(2-cyclohexylethyl)- Structure

Benzene,(2-cycl...

Cyclohexane,1,1'-(1,2-ethanediyl)bis- Structure

Cyclohexane,1,1...

Bibenzyl Structure

1,2-bis(2-fluorophenyl)ethane-1,2-dione Structure

1,2-bis(2-fluor...

~47%

Benzene,(2-cyclohexylethyl)- Structure

Benzene,(2-cycl...

Cyclohexane,1,1'-(1,2-ethanediyl)bis- Structure

Cyclohexane,1,1...

Bibenzyl Structure

4,4'-Dichloro benzil Structure

4,4'-Dichloro benzil

~50%

Benzene,(2-cyclohexylethyl)- Structure

Benzene,(2-cycl...

Cyclohexane,1,1'-(1,2-ethanediyl)bis- Structure

Cyclohexane,1,1...

Bibenzyl Structure

4,4'-dibromobenzil Structure

4,4'-dibromobenzil

~23%

Benzene,(2-cyclohexylethyl)- Structure

Benzene,(2-cycl...

Cyclohexane,1,1'-(1,2-ethanediyl)bis- Structure

Cyclohexane,1,1...

Bibenzyl Structure

1,2-bis(2-fluorophenyl)ethane-1,2-dione Structure

1,2-bis(2-fluor...

~27%

Benzene,(2-cyclohexylethyl)- Structure

Benzene,(2-cycl...

Cyclohexane,1,1'-(1,2-ethanediyl)bis- Structure

Cyclohexane,1,1...

Bibenzyl Structure

1,2-DIBENZOYLETHANE Structure

1,2-DIBENZOYLETHANE

~18%

1,4-Diphenylbutane Structure

1,4-Diphenylbutane

4-cyclohexylbutylcyclohexane Structure

4-cyclohexylbut...

1-cyclohexyl-4-phenylbutane Structure

1-cyclohexyl-4-...

1,4-Dibenzoylbutane Structure

1,4-Dibenzoylbutane

~20%

1-cyclohexyl-6-phenylhexane Structure

1-cyclohexyl-6-...

Benzene,1,1'-(1,6-hexanediyl)bis- Structure

Benzene,1,1'-(1...

1,6-Dicyclohexylhexane Structure

1,6-Dicyclohexy...

4,4'-dimethylbenzil Structure

4,4'-dimethylbenzil

~83%

1,2-di(p-tolyl)ethane Structure

1,2-di(p-tolyl)...

4,4'-di-tert-butylbenzil Structure

4,4'-di-tert-bu...

~86%

1-tert-butyl-4-[2-(4-tert-butylphenyl)ethyl]benzene Structure

1-tert-butyl-4-...

1,3-Dibenzoylpropane Structure

1,3-Dibenzoylpropane

~44%

1-cyclohexyl-5-phenylpentane Structure

1-cyclohexyl-5-...

5-phenylpentylbenzene Structure

5-phenylpentylb...

1,1'-(1,5-Pentanediyl)biscyclohexane Structure

1,1'-(1,5-Penta...