Journal of Organometallic Chemistry

Synthèse de biaryles dissymétriques par électroréduction d'halogénures aromatiques catalysée par des complexes du nickel associé à la 2, 2′-bipyridine

G Meyer, M Troupel, J Périchon

Index: Meyer, Gilbert; Troupel, Michel; Perichon, Jacques Journal of Organometallic Chemistry, 1990 , vol. 393, # 1 p. 137 - 142

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Citation Number: 31

Abstract

Abstract Nickel-2-2′-bipyridine complexes are useful catalysts in the preparation of unsymmetrical biaryls by electroreduction of a mixture of two aryl halides which are para- substituted with electron acceptors and electron donors, respectively. The syntheses were carried out in N-methylpyrrolidone by constant current electrolyses in an undivided cell fitted with a sacrificial magnesium anode.