Strongly Blue Luminescent Cationic Iridium (III) Complexes with an Electron??Rich Ancillary Ligand: Evaluation of Their Optoelectronic and Electrochemiluminescence …

…, KN Swanick, S Gallagher??Duval…

Index: Ladouceur, Sebastien; Swanick, Kalen N.; Gallagher-Duval, Shawn; Ding, Zhifeng; Zysman-Colman, Eli European Journal of Inorganic Chemistry, 2013 , # 30 p. 5329 - 5343

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Citation Number: 21

Abstract

Abstract Two strongly blue luminescent cationic heteroleptic iridium complexes 1b and 2b bearing a 4, 4′-bis (dimethylamino)-2, 2′-bipyridine (dmabpy) ancillary ligand and either 1-benzyl-4-(2, 4-difluorophenyl)-1H-1, 2, 3-triazole (dFphtl) or 2-(2, 4-difluorophenyl)-5- methylpyridine (dFMeppyH), respectively, have been synthesized and fully characterized. In comparison with other analogues, the interplay of the triazole unit with the dmabpy unit ...