Green Chemistry

Retracted article: Cross coupling in water: Suzuki–Miyaura vinylation and difluorovinylation of arylboronic acids

J Pschierer, N Peschek, H Plenio

Index: Pschierer, Jan; Peschek, Natalie; Plenio, Herbert Green Chemistry, 2010 , vol. 12, # 4 p. 636 - 642

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Citation Number: 6

Abstract

We recently reported that a water-soluble disulfonated fluorenylphosphine/palladium complex displays excellent activities in Suzuki–Miyaura reactions of various aryl chlorides when using water 21,22 or water/n-butanol 23,24 as solvents. 25 This protocol appears to be especially efficient for substrates containing difficult (potentially palladium coordinating) functional groups and unreactive C–X bonds. ... We report here a simple coupling protocol utilizing Na 2 PdCl 4 and the ...

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