Organic letters

Enantioselective Synthesis of 2, 3-Disubstituted Indanones via Pd-Catalyzed Intramolecular Asymmetric Allylic Alkylation of Ketones

XH Li, BH Zheng, CH Ding, XL Hou

Index: Yang, Xiao-Fei; Ding, Chang-Hua; Li, Xiao-Hui; Huang, Jian-Qiang; Hou, Xue-Long; Dai, Li-Xin; Wang, Pin-Jie Journal of Organic Chemistry, 2012 , vol. 77, # 20 p. 8980 - 8985,6 Title/Abstract Full Text Show Details Yang, Xiao-Fei; Ding, Chang-Hua; Li, Xiao-Hui; Huang, Jian-Qiang; Hou, Xue-Long; Dai, Li-Xin; Wang, Pin-Jie Journal of Organic Chemistry, 2012 , vol. 77, # 20 p. 8980 - 8985

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Citation Number: 13

Abstract

A Pd-catalyzed intramolecular asymmetric allylic alkylation (AAA) reaction with “hard” carbanions has been developed for the first time, affording 2, 3-disubstituted indanones with high diastereo-and enantioselectivities. The transformation of these products into other core

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