1, 1-Bis (benzenesulfonyl) cyclopropane: a synthon for a propylene 1, 3-dipole

BM Trost, J Cossy, J Burks

Index: Trost, Barry M.; Cossy, Janine; Burks, John Journal of the American Chemical Society, 1983 , vol. 105, # 4 p. 1052 - 1054

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Citation Number: 23

Abstract

2 PhSH NaH It CH, I 7, PhS, CH, a Number in parentheses represents yield of recrystallized product. of 2 equivalent to a carbocationic center. Simultaneously, an anionic center is created at C (1) for further elaboration. The pioneering work of Danishefsky on developing 1, l-dicarboalkoxycyclopropanes takes advantage of the carbocationic character of Z5 but does not provide facile manipulation of the anionic enter since removal of the carboalkoxy ...