Synthetic Communications

Mild, efficient, and greener dethioacetalization protocol using 30% hydrogen peroxide in catalytic combination with ammonium iodide

NC Ganguly, P Mondal

Index: Ganguly, Nemai C.; Mondal, Pallab Synthetic Communications, 2011 , vol. 41, # 16 p. 2374 - 2384

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Citation Number: 8

Abstract

Abstract A simple, mild, efficient, and expedient greener dethioacetalization protocol employing a catalytic amount of nontoxic ammonium iodide (10 mol%) in combination with 30% hydrogen peroxide as terminal oxidizer is revealed. The reagent accomplished facile deprotection of 1, 3-dithianes and dithiolanes of activated aromatic substrates in an aqueous medium in the presence of sodium dodecylsulfate (SDS) at room temperature under ...