Palladium-catalyzed reduction of aryl sulfonates. Reduction versus hydrolysis selectivity control

…, S De Bernardinis, F Francalanci, S Penco…

Index: Cabri, Walter; Bernardinis, Silvia De; Francalanci, Franco; Penco, Sergio; Santi, Roberto Journal of Organic Chemistry, 1990 , vol. 55, # 1 p. 350 - 353

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Citation Number: 58

Abstract

Deoxygenation of phenols appears to be an important tool in the field of organic synthesis; l palladium-catalyzed reduction of perfluoroalkane sulfonates has arisen in the last few years as an important method with mild reaction conditions and concomitant high chemoselectivity. 2 However, the synthesis of perfluoroalkane sulfonates from the corresponding phenols can sometimes be a major problem3 in terms of selectivity, ...