e.g. Filippa Pettersson or Cancer Res. 75(6) , 1102-12, (2015) or 10.1002/anie.201600521

Journal of the American Chemical Society

Rate of Oxidation of Aromatic Hydrocarbons by Lead Tetraacetate1

LF Fieser, ST Putnam

Index: Fieser; Putnam Journal of the American Chemical Society, 1947 , vol. 69, p. 1041,1044

Full Text: HTML

Citation Number: 6

Abstract

Summary It has been found that the first step in the oxidation of anthracene with lead tetraacetate consists in the addition of acetoxyl groups to the two meso positions to give a mixture of the cis and trans isomers. Both substances lose acetic acid readily and yield 9- acetoxyanthracene, and this substance on further oxidation again adds two acetoxyl groups to give an intermediate that easily loses acetic anhydride to yield oxanthrone acetate. The ...

9,19-Dibromo-9,10-dihydroanthracene Structure

9,19-Dibromo-9,...

Silver acetate Structure

~%

9-Anthracenol,9-acetate Structure

9-Anthracenol,9...

(10-acetyloxy-9,10-dihydroanthracen-9-yl) acetate Structure

(10-acetyloxy-9...

~%

9-Anthracenol,9-acetate Structure

9-Anthracenol,9...

9,19-Dibromo-9,10-dihydroanthracene Structure

9,19-Dibromo-9,...

Silver acetate Structure

acetic acid Structure

~%

9-Anthracenol,9-acetate Structure

9-Anthracenol,9...

trans-9.10-diacetoxy-9.10-dihydro-anthracene Structure

trans-9.10-diac...

acetic acid Structure

~%

9-Anthracenol,9-acetate Structure

9-Anthracenol,9...

cis-9.10-diacetoxy-9.10-dihydro-anthracene Structure

cis-9.10-diacet...

acetic acid Structure

~%

9-Anthracenol,9-acetate Structure

9-Anthracenol,9...

Sodium acetate Structure

Ethanoic anhydride Structure

Ethanoic anhydride

Anthraquinone Structure

~%

9-Anthracenol,9-acetate Structure

9-Anthracenol,9...

Detail

9,9,10-triacetoxy-9,10-dihydro-anthracene Structure

9,9,10-triaceto...

~%

9,10-Diacetoxyanthracene Structure

9,10-Diacetoxya...

9-Anthracenol,9-acetate Structure

9-Anthracenol,9...

~%

9,10-Diacetoxyanthracene Structure

9,10-Diacetoxya...

9,19-Dibromo-9,10-dihydroanthracene Structure

9,19-Dibromo-9,...

~%

9,10-Diacetoxyanthracene Structure

9,10-Diacetoxya...

Anthracene Structure

~%

9,10-Diacetoxyanthracene Structure

9,10-Diacetoxya...

9,9,10-triacetoxy-9,10-dihydro-anthracene Structure

9,9,10-triaceto...

acetic acid Structure

~%

acetic acid 10-oxo-9,10-dihydro-anthracen-9-yl ester Structure

acetic acid 10-...

9,10-Diacetoxyanthracene Structure

9,10-Diacetoxya...

9-Anthracenol,9-acetate Structure

9-Anthracenol,9...

lead tetraacetate Structure

lead tetraacetate

benzene Structure

~%

acetic acid 10-oxo-9,10-dihydro-anthracen-9-yl ester Structure

acetic acid 10-...

Detail

Sodium acetate Structure

Ethanoic anhydride Structure

Ethanoic anhydride

Anthraquinone Structure

~%

9-Anthracenol,9-acetate Structure

9-Anthracenol,9...

Detail

Biaryls in nature: a multi-facetted class of stereochemicall...

[Majumder, P. L.; Joardar, M. Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1983 , vol. 22, # 12 p. 1191 - 1193]

Manganese (III)-Mediated Formylation of Aromatic Compounds i...

[Nishino, Hiroshi; Tsunoda, Katsunori; Kurosawa, Kazu Bulletin of the Chemical Society of Japan, 1989 , vol. 62, # 2 p. 545 - 550]

Manganese (III)-Mediated Formylation of Aromatic Compounds i...

[Nishino, Hiroshi; Tsunoda, Katsunori; Kurosawa, Kazu Bulletin of the Chemical Society of Japan, 1989 , vol. 62, # 2 p. 545 - 550]

Manganese (III)-Mediated Formylation of Aromatic Compounds i...

[Nishino, Hiroshi; Tsunoda, Katsunori; Kurosawa, Kazu Bulletin of the Chemical Society of Japan, 1989 , vol. 62, # 2 p. 545 - 550]

Manganese (III)-Mediated Formylation of Aromatic Compounds i...

[Nishino, Hiroshi; Tsunoda, Katsunori; Kurosawa, Kazu Bulletin of the Chemical Society of Japan, 1989 , vol. 62, # 2 p. 545 - 550]