Reactions of aliphatic halides with solutions of alkali metals in liquid ammonia: II. The behaviour of some arylcarbinyl chlorides towards solutions of sodium in liquid …

PE Verkade, KS De Vries…

Index: Verkade,P.E. et al. Recueil des Travaux Chimiques des Pays-Bas, 1963 , vol. 82, p. 637 - 650

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Citation Number: 6

Abstract

The behaviour of some primary, secondary, and tertiary arylcarbinyl chlorides towards solutions of sodium in liquid ammonia has been studied. Particular attention has been devoted to the biaralkyls formed. ... Introduction it was found that in the reaction between an alkyl chloride and a solution of sodium or lithium in liquid ammonia no appreciable formation of bialkyl takes place. It was therefore very curious for us to learn from the literature that Dean and Berchet 2 , when ...

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