Cross-coupling reactions of phenylmagnesium halides with fluoroazines and fluorodiazines

…, B Guillamet, F Trécourt, G Quéguiner

Index: Mongin, Florence; Mojovic, Ljubica; Guillamet, Benoit; Trecourt, Francois; Queguiner, Guy Journal of Organic Chemistry, 2002 , vol. 67, # 25 p. 8991 - 8994

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Citation Number: 126

Abstract

The first nickel-catalyzed cross-coupling reactions between fluoroarenes and aryl organometallics using commercially available ligands are described. The nickel-catalyzed cross-coupling reactions between aryl Grignard reagents and fluoroazines and-diazines occurred in THF at room temperature using commercially available 1, 2-bis (diphenylphosphino) ethane, 1, 3-bis (diphenylphosphino) propane, or 1, 1'-bis ( ...

~61%

~60%

~80%

~97%

~90%

~79%

~65%

Syntheses of substituted pyridines, quinolines and diazines ...

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