Chemistry–A European Journal

Pd??Catalyzed Reaction of Allyl Carbonate with Polyols: The Role of CO2 in Transesterification versus Etherification of Glycerol

A Gordillo, GC Lloyd??Jones

Index: Gordillo, Alvaro; Lloyd-Jones, Guy C. Chemistry - A European Journal, 2012 , vol. 18, # 9 p. 2660 - 2665

Full Text: HTML

Citation Number: 7

Abstract

Abstract An intermolecular Pd/PPh 3-catalyzed transesterification of diallyl carbonate with glycerol to generate glycerol carbonate has been developed. Analysis of the reaction kinetics in THF indicates a first-order dependence on Pd and diallyl carbonate, that the Pd

~86%

~94%

~21%

~15%

~6%

~9%

Detail

~83%

Detail

~46%

Detail

Metal??Free Synthesis of Cyclic and Acyclic Carbonates from ...

[Lim, Yu Na; Lee, Chan; Jang, Hye-Young European Journal of Organic Chemistry, 2014 , vol. 2014, # 9 p. 1823 - 1826]

Inter-and intramolecular phosphonium salt cocatalysis in cyc...

[North, Michael; Villuendas, Pedro; Young, Carl Tetrahedron Letters, 2012 , vol. 53, # 22 p. 2736 - 2740]

Catalytic performance of polymer-supported ionic liquids in ...

[Kim, Dong-Woo; Park, Moon-Seok; Selvaraj, Manickam; Park, Gyung-Ah; Lee, Sun-Do; Park, Dae-Won Research on Chemical Intermediates, 2011 , vol. 37, # 9 p. 1305 - 1312]

Fast monomers: factors affecting the inherent reactivity of ...

[Jansen, Johan F. G. A.; Dias, Aylvin A.; Dorschu, Marko; Coussens, Betty Macromolecules, 2003 , vol. 36, # 11 p. 3861 - 3873]

The allyloxycarbonyl group for alcohol protection: quantitat...

[Guibe, F.; Saint M'Leux, Y. Tetrahedron Letters, 1981 , vol. 22, # 37 p. 3591 - 3594]