Chemistry–A European Journal

Pd??Catalyzed Reaction of Allyl Carbonate with Polyols: The Role of CO2 in Transesterification versus Etherification of Glycerol

A Gordillo, GC Lloyd??Jones

文献索引：Gordillo, Alvaro; Lloyd-Jones, Guy C. Chemistry - A European Journal, 2012 , vol. 18, # 9 p. 2660 - 2665

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被引用次数: 7

摘要

Abstract An intermolecular Pd/PPh 3-catalyzed transesterification of diallyl carbonate with glycerol to generate glycerol carbonate has been developed. Analysis of the reaction kinetics in THF indicates a first-order dependence on Pd and diallyl carbonate, that the Pd