The Chemistry of Sulfur Tetrafluoride. II. The Fluorination of Organic Carbonyl Compounds1

WR Hasek, WC Smith…

Index: Hasek,W.R. et al. Journal of the American Chemical Society, 1960 , vol. 82, p. 543 - 551

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Citation Number: 260

Abstract

> C= O+ SF4+) CF2+ SOF? with a variety of carbonyl compounds including aldehydes, ketones and carboxylic acids. Discovery of this reaction, one of few reactions useful for introduction of fluorine at a specific site in a molecule, makes available many new or relatively inaccessible fluorine compounds. Reactions of SF4 with the various classes of organic carbonyl compounds are discussed in the following sections. Carboxylic Acids.-In ...

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