Journal of Organometallic Chemistry

NHC–Pd (II)–Im (NHC= N-heterocyclic carbene; Im= 1-methylimidazole) complex catalyzed Hiyama reaction of aryl chlorides with aryltrimethoxysilanes

ZS Gu, LX Shao, JM Lu

Index: Gu, Zheng-Song; Shao, Li-Xiong; Lu, Jian-Mei Journal of Organometallic Chemistry, 2012 , vol. 700, p. 132 - 134

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Citation Number: 3

Abstract

A well-defined NHC–Pd (II)–Im complex was proved to be an efficient catalyst for the Hiyama reaction of a variety of aryl chlorides with aryltrimethoxysilanes. Under the optimal conditions, all reactions took place smoothly to give the corresponding coupling products in moderate to high yields.

~71%

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