Sustainable Catalysis: Rational Pd Loading on MIL??101Cr??NH2 for More Efficient and Recyclable Suzuki–Miyaura Reactions

V Pascanu, Q Yao, A Bermejo Gómez…

Index: Pascanu, Vlad; Yao, Qingxia; Bermejo Gomez, Antonio; Gustafsson, Mikaela; Yun, Yifeng; Wan, Wei; Samain, Louise; Zou, Xiaodong; Martin-Matute, Belen Chemistry - A European Journal, 2013 , vol. 19, # 51 p. 17483 - 17493

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Citation Number: 50

Abstract

Abstract Palladium nanoparticles have been immobilized into an amino-functionalized metal– organic framework (MOF), MIL-101Cr-NH 2, to form Pd@ MIL-101Cr-NH 2. Four materials with different loadings of palladium have been prepared (denoted as 4-, 8-, 12-, and 16 wt% Pd@ MIL-101Cr-NH 2). The effects of catalyst loading and the size and distribution of the Pd nanoparticles on the catalytic performance have been studied. The catalysts were ...

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