Journal of Organometallic Chemistry

NHC–Pd (II)–Im (NHC= N-heterocyclic carbene; Im= 1-methylimidazole) complexes as efficient catalysts for Suzuki-Miyaura coupling reactions of aryl chlorides

YQ Tang, JM Lu, LX Shao

Index: Tang, Yi-Qiang; Lu, Jian-Mei; Shao, Li-Xiong Journal of Organometallic Chemistry, 2011 , vol. 696, # 23 p. 3741 - 3744

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Citation Number: 4

Abstract

A new type of well-defined N-heterocyclic carbene (NHC)-palladium chloride-imidazole complexes derived from IPrHCl or IMesHCl, PdCl2 and 1-methylimidazole exhibits high catalytic activity in the room-temperature Suzuki-Miyaura coupling reactions of aryl or heteroaryl chlorides. Moreover, the large-scale (20.0 mmol) couplings in the presence of 0.01 mol% catalyst loading can also give the corresponding coupling products in high ...

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