Synthesis, structure and reactivity of hydrated and dehydrated organotin cations

V Chandrasekhar, R Boomishankar…

Index: Chandrasekhar, Vadapalli; Boomishankar, Ramamoorthy; Gopal, Kandasamy; Sasikumar, Palani; Singh, Puja; Steiner, Alexander; Zacchini, Stefano European Journal of Inorganic Chemistry, 2006 , # 20 p. 4129 - 4136

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Citation Number: 15

Abstract

Abstract Monomeric organotin dications {[nBu 2 Sn (H 2 O) 4] 2+· 2C 6 H 5 SO 3–} and {[nBu 2 Sn (H 2 O) 4] 2+· 1, 5-C 10 H 6 (SO 3–) 2} have been synthesized by the reaction of [nBu 2 SnO] n and the corresponding arylsulfonic acid. Dodecanuclear organooxotin macrocations {[(nBuSn) 12 (μ 3-O) 14 (μ 2-OH) 6] 2+· 2RSO 3–}(R= C 6 H 5; 2, 5-Me 2 C 6 H 3) have been synthesized by the reaction of nBuSn (O)(OH) and the corresponding arylsulfonic acid. ...