The Journal of organic chemistry

Oxidation of Alkynes by the HOF⊙ CH3CN Complex

S Dayan, I Ben-David, S Rozen

Index: Journal of Organic Chemistry, , vol. 65, # 25 p. 8816 - 8818

Full Text: HTML

Citation Number: 51

Abstract

... July 20, 2000 The HOF‚CH3CN complex discovered over a decade ago1 is probably the best oxygen transfer agent organic chemistry has to ... It reacts very efficiently with a large variety of organic compounds resulting either in their oxidation or in transferring an oxygen ... J. Org. ...

 Related Synthetic Route
4-Octyne Structure

1942-45-6

4-Octyne

~9%

4-Heptanone Structure

123-19-3

4-Heptanone

4,5-Octadione Structure

5455-24-3

4,5-Octadione

α,β-epoxy-4-octanone Structure

5162-93-6

α,β-epoxy-4-octanone

4-Chlorophenylacetylene Structure

873-73-4

4-Chlorophenyla...

~83%

4-Chlorobenzaldehyde Structure

104-88-1

4-Chlorobenzaldehyde

4-Chlorobenzoic acid Structure

74-11-3

4-Chlorobenzoic acid

4-Ethynyltoluene Structure

766-97-2

4-Ethynyltoluene

~80%

p-Tolualdehyde Structure

104-87-0

p-Tolualdehyde

4-Methylbenzoic acid Structure

99-94-5

4-Methylbenzoic acid

Oct-1-yne Structure

629-05-0

Oct-1-yne

~20%

Heptanal Structure

111-71-7

Heptanal

n-heptanoic acid Structure

111-14-8

n-heptanoic acid

2-oxooctanal Structure

2363-86-2

2-oxooctanal

Detail
4-Phenyl-3-butyn-2-one Structure

1817-57-8

4-Phenyl-3-buty...

~92%

1-Phenylpropane-1,2-dione Structure

579-07-7

1-Phenylpropane...

Oct-1-yne Structure

629-05-0

Oct-1-yne

~%

(2E)-2-Octenal Structure

2548-87-0

(2E)-2-Octenal

(Z)-2-octen-1-al Structure

20664-46-4

(Z)-2-octen-1-al

Oct-1-yne Structure

629-05-0

Oct-1-yne

~4%

Heptanal Structure

111-71-7

Heptanal

n-heptanoic acid Structure

111-14-8

n-heptanoic acid

2-oxooctanal Structure

2363-86-2

2-oxooctanal

Detail
Hept-1-yne Structure

628-71-7

Hept-1-yne

~5%

2-oxo-1-heptanal Structure

2363-85-1

2-oxo-1-heptanal

Hexanal Structure

66-25-1

Hexanal

2,3-epoxyheptanal Structure

58936-30-4

2,3-epoxyheptanal

Detail
Hept-1-yne Structure

628-71-7

Hept-1-yne

~20%

2-oxo-1-heptanal Structure

2363-85-1

2-oxo-1-heptanal

Hexanal Structure

66-25-1

Hexanal

2,3-epoxyheptanal Structure

58936-30-4

2,3-epoxyheptanal

Detail
4-Ethynyltoluene Structure

766-97-2

4-Ethynyltoluene

~8%

p-Tolualdehyde Structure

104-87-0

p-Tolualdehyde

4-Methylbenzoic acid Structure

99-94-5

4-Methylbenzoic acid

Hept-1-yne Structure

628-71-7

Hept-1-yne

~%

Heptenal Structure

18829-55-5

Heptenal

2-Heptenal Structure

57266-86-1

2-Heptenal


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