Dithio??und Thionester, 50. α, β??Acetylenische Thioamide, Dithioester und Thionester

K Hartke, HD Gerber, U Roesrath

Index: Hartke, Klaus; Gerber, Hans-Dieter; Roesrath, Ulrich Liebigs Annalen der Chemie, 1991 , # 9 p. 903 - 916

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Citation Number: 13

Abstract

Dithio and Thiono Esters, 50').-a $-Acetylenic Thioamides, Dithio Esters, and Thiono Esters a, P-Acetylenic amides 5 and thioamides? have been obtained sation of the terminal acetylenes 3 with methyl carbonodiby a palladium-catalysed condensation of the terminal acet-thiochloridate (25) or 0-methyl carbonothiochloridate (26). ylenes 3 with N, N- dimethylcarbamoyl chloride (4) or-thiocar-The thiono esters 23 are also accessible from ...