Synlett

Montmorillonite clays in organic synthesis: a one-pot conversion of phenols to 2, 2-dimethylbenzopyrans

MR Dintzner, KM McClelland, KM Morse, MH Akroush

Index: Dintzner, Matthew R.; McClelland, Kristen M.; Morse, Kara M.; Akroush, Michael H. Synlett, 2004 , # 11 p. 2028 - 2030

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Citation Number: 19

Abstract

In conjunction with ongoing efforts in our laboratories aimed at the application of environmentally benign clays in organic synthesis, we have developed a convenient clay-catalyzed route to benzopyran derivatives that may be applied in the synthesis of benzopyran-containing natural products. Although clays have been shown to successfully catalyze a variety of organic reactions, [4] they are somewhat under-exploited in natural products synthesis, [5] perhaps because their specific modes of ...