e.g. Filippa Pettersson or Cancer Res. 75(6) , 1102-12, (2015) or 10.1002/anie.201600521

Selective oxidation of allylic sulfides by hydrogen peroxide with the trirutile-type solid oxide catalyst LiNbMoO6

S Choi, JD Yang, M Ji, H Choi, M Kee…

Index: Julia, Marc; Nel, Maurice; Uguen, Daniel Bulletin de la Societe Chimique de France, 1987 , # 3 p. 487 - 492

Full Text: HTML

Citation Number: 58

Abstract

... 1 Among the various transformations of organic sulfides, chemoselective oxidation to sulfoxides or to sulfones has been widely studied with regard to extending the carbon skeleton 2 and/or double bond formation 3 using the resulting sulfoxides or sulfones. ...

p-Cresol Structure

1-methyl-4-(3-methylbut-2-enylsulfonyl)benzene Structure

1-methyl-4-(3-m...

~51%

2,2,6-trimethyl-3,4-dihydrochromene Structure

2,2,6-trimethyl...

p-Cresol Structure

1-methyl-4-(2-methylbut-3-en-2-ylsulfonyl)benzene Structure

1-methyl-4-(2-m...

~50%

2,2,6-trimethyl-3,4-dihydrochromene Structure

2,2,6-trimethyl...

1-methyl-4-(3-methylbut-2-enylsulfonyl)benzene Structure

1-methyl-4-(3-m...

Butylmagnesium Bromide Structure

Butylmagnesium ...

1-methyl-4-(2-methylbut-3-en-2-ylsulfonyl)benzene Structure

1-methyl-4-(2-m...

~10%

2,2,6-trimethyl-3,4-dihydrochromene Structure

2,2,6-trimethyl...

4-methyl-2-(3-methylbut-2-enyl)phenol Structure

4-methyl-2-(3-m...

1-methyl-4-(2-methylbut-3-en-2-ylsulfonyl)benzene Structure

1-methyl-4-(2-m...

4-Methylphenoxymagnesiumbromid Structure

4-Methylphenoxy...

~11%

2,2,6-trimethyl-3,4-dihydrochromene Structure

2,2,6-trimethyl...

4-methyl-2-(3-methylbut-2-enyl)phenol Structure

4-methyl-2-(3-m...

1-methyl-4-(2-methylbut-3-en-2-ylsulfonyl)benzene Structure

1-methyl-4-(2-m...

~%

2,2,6-trimethyl-3,4-dihydrochromene Structure

2,2,6-trimethyl...

Butylmagnesium Bromide Structure

Butylmagnesium ...

1-methyl-4-(2-methylbut-3-en-2-ylsulfonyl)benzene Structure

1-methyl-4-(2-m...

~91%

2-METHYL-2-OCTENE Structure

2-METHYL-2-OCTENE

1-methyl-4-(2-methylbut-3-en-2-ylsulfonyl)benzene Structure

1-methyl-4-(2-m...

Phenyllithium Structure

~97%

3-methylbut-2-enylbenzene Structure

3-methylbut-2-e...

1-methyl-4-(2-methylbut-3-en-2-ylsulfonyl)benzene Structure

1-methyl-4-(2-m...

LITHIUM THIOPHENOXIDE Structure

LITHIUM THIOPHE...

~90%

Benzene,[(3-methyl-2-buten-1-yl)thio]- Structure

Benzene,[(3-met...

1-methyl-4-(2-methylbut-3-en-2-ylsulfonyl)benzene Structure

1-methyl-4-(2-m...

thiophenylmagnesium bromide Structure

thiophenylmagne...

~76%

Benzene,[(3-methyl-2-buten-1-yl)thio]- Structure

Benzene,[(3-met...

1-methyl-4-(2-methylbut-3-en-2-ylsulfonyl)benzene Structure

1-methyl-4-(2-m...

Thiophenol Structure

~54%

Benzene,[(3-methyl-2-buten-1-yl)thio]- Structure

Benzene,[(3-met...

1-methyl-4-(3-methylbut-2-enylsulfonyl)benzene Structure

1-methyl-4-(3-m...

Detail

1-methyl-4-(2-methylbut-3-en-2-ylsulfonyl)benzene Structure

1-methyl-4-(2-m...

Thiophenol Structure

~14%

Benzene,[(3-methyl-2-buten-1-yl)thio]- Structure

Benzene,[(3-met...

1-methyl-4-(3-methylbut-2-enylsulfonyl)benzene Structure

1-methyl-4-(3-m...

Detail

p-Cresol Structure

1-methyl-4-(2-methylbut-3-en-2-ylsulfonyl)benzene Structure

1-methyl-4-(2-m...

~18%

2,2,6-trimethyl-3,4-dihydrochromene Structure

2,2,6-trimethyl...

1-methyl-4-(3-methylbut-2-enylsulfonyl)benzene Structure

1-methyl-4-(3-m...

2,3,5-Trimethyl-1,4-benzenediol Structure

2,3,5-Trimethyl...

1-methyl-4-(2-methylbut-3-en-2-ylsulfonyl)benzene Structure

1-methyl-4-(2-m...

~40%

2H-1-Benzopyran-6-ol,3,4-dihydro-2,2,5,7,8-pentamethyl- Structure

2H-1-Benzopyran...

1-methyl-4-(3-methylbut-2-enylsulfonyl)benzene Structure

1-methyl-4-(3-m...

2,3,5-Trimethyl-1,4-benzenediol Structure

2,3,5-Trimethyl...

1-methyl-4-(2-methylbut-3-en-2-ylsulfonyl)benzene Structure

1-methyl-4-(2-m...

~5%

2H-1-Benzopyran-6-ol,3,4-dihydro-2,2,5,7,8-pentamethyl- Structure

2H-1-Benzopyran...

para-Tolyl disulfide Structure

para-Tolyl disulfide

Detail

Butylmagnesium Bromide Structure

Butylmagnesium ...

1-methyl-4-(2-methylbut-3-en-2-ylsulfonyl)benzene Structure

1-methyl-4-(2-m...

~29%

2,2,6-trimethyl-3,4-dihydrochromene Structure

2,2,6-trimethyl...

4-methyl-2-(3-methylbut-2-enyl)phenol Structure

4-methyl-2-(3-m...

1-methyl-4-(2-methylbut-3-en-2-ylsulfonyl)benzene Structure

1-methyl-4-(2-m...

4-Methylphenoxymagnesiumbromid Structure

4-Methylphenoxy...

~29%

2,2,6-trimethyl-3,4-dihydrochromene Structure

2,2,6-trimethyl...

4-methyl-2-(3-methylbut-2-enyl)phenol Structure

4-methyl-2-(3-m...

2,3,5-Trimethyl-1,4-benzenediol Structure

2,3,5-Trimethyl...

1-methyl-4-(2-methylbut-3-en-2-ylsulfonyl)benzene Structure

1-methyl-4-(2-m...

~68%

2H-1-Benzopyran-6-ol,3,4-dihydro-2,2,5,7,8-pentamethyl- Structure

2H-1-Benzopyran...

2-p-tolyl-thio-3,5-trimethylhydroquinone Structure

2-p-tolyl-thio-...

2,3,5-Trimethyl-1,4-benzenediol Structure

2,3,5-Trimethyl...

1-methyl-4-(2-methylbut-3-en-2-ylsulfonyl)benzene Structure

1-methyl-4-(2-m...

~23%

2H-1-Benzopyran-6-ol,3,4-dihydro-2,2,5,7,8-pentamethyl- Structure

2H-1-Benzopyran...

1-methyl-4-(3-methylbut-2-enylsulfonyl)benzene Structure

1-methyl-4-(3-m...

2,3,5-Trimethyl-1,4-benzenediol Structure

2,3,5-Trimethyl...

1-methyl-4-(2-methylbut-3-en-2-ylsulfonyl)benzene Structure

1-methyl-4-(2-m...

~37%

2H-1-Benzopyran-6-ol,3,4-dihydro-2,2,5,7,8-pentamethyl- Structure

2H-1-Benzopyran...

para-Tolyl disulfide Structure

para-Tolyl disulfide

Detail

1-methyl-4-(2-methylbut-3-en-2-ylsulfonyl)benzene Structure

1-methyl-4-(2-m...

~%

3-methylbut-2-enylsulfonylbenzene Structure

3-methylbut-2-e...

An improved method for synthesis of 1-benzopyrans from unsat...

[Ishino; Mihara; Hayakawa; Miyata; Kaneko Synthetic Communications, 2001 , vol. 31, # 3 p. 439 - 448]

Montmorillonite clays in organic synthesis: a one-pot conver...

[Dintzner, Matthew R.; McClelland, Kristen M.; Morse, Kara M.; Akroush, Michael H. Synlett, 2004 , # 11 p. 2028 - 2030]