Tetrahedron Letters

A class of new silylating agents. II. A highly reactive reagent for introduction of the trimethylsilyl group.

T Veysoglu, LA Mitscher

Index: Veysoglu, Tarik; Mitscher, Lester A. Tetrahedron Letters, 1981 , vol. 22, # 14 p. 1303 - 1306

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Citation Number: 22

Abstract

Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... Trimethylsilyl enol ethers of pentane-2,4-dione and methyl acetoacetate react rapidly with alcohols at room temperature without the need for catalytic assistance to give high isolated yields of trimethylsilyl ethers. ... The reactions were monitored and purity was established in all cases using a ...

~82%

~86%

~81%

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