The Journal of organic chemistry

A novel, chemoselective and efficient microwave-assisted deprotection of silyl ethers with selectfluor

STA Shah, S Singh, PJ Guiry

Index: Saxena, Ira; Deka, Nabajyoti; Sarma, Jadab C.; Tsuboi, Sadao Synthetic Communications, 2003 , vol. 33, # 23 p. 4005 - 4011

Full Text: HTML

Citation Number: 30

Abstract

... In this communication, we wish to report the desilylation of a wide range of silyl-protected primary ... ether (5S,6R)-methyl 5,6-bis(tert-butyldimethylsilyl-oxy)oct-7-enoate as a key synthetic intermediate.(20 ... to afford the corresponding diol in 97% yield after 10 min at 150 °C, entry 6a. ...

 Related Synthetic Route
Chlorotrimethylsilane Structure

75-77-4

Chlorotrimethyl...

1-Docosanol Structure

661-19-8

1-Docosanol

~93%

docosoxy(trimethyl)silane Structure

42449-18-3

docosoxy(trimet...

Cyclohexene, 1-methyl-4-[1-methyl-1-[(trimethylsilyl)oxy]ethyl] Structure

90934-33-1

Cyclohexene, 1-...

~99%

Terpineol Structure

98-55-5

Terpineol

tert-butyldimethyl((2-(4-methylcyclohex-3-en-1-yl)propan-2-yl)oxy)silane Structure

809240-22-0

tert-butyldimet...

~99%

Terpineol Structure

98-55-5

Terpineol

Chlorotrimethylsilane Structure

75-77-4

Chlorotrimethyl...

Linalool Structure

78-70-6

Linalool

~90%

3,7-dimethylocta-1,6-dien-3-yloxy(trimethyl)silane Structure

59632-77-8

3,7-dimethyloct...

3-(tert-butyldimethylsiloxy)-3,7-dimethyl-1,6-octadiene Structure

89155-68-0

3-(tert-butyldi...

~98%

Linalool Structure

78-70-6

Linalool

3,7-dimethylocta-1,6-dien-3-yloxy(trimethyl)silane Structure

59632-77-8

3,7-dimethyloct...

~99%

Linalool Structure

78-70-6

Linalool

tert-butyl(hexadecyloxy)dimethylsilane Structure

76358-80-0

tert-butyl(hexa...

~99%

1-Hexadecanol Structure

36653-82-4

1-Hexadecanol

hexadecoxy(trimethyl)silane Structure

6221-90-5

hexadecoxy(trim...

~99%

1-Hexadecanol Structure

36653-82-4

1-Hexadecanol

Chlorotrimethylsilane Structure

75-77-4

Chlorotrimethyl...

1-Hexadecanol Structure

36653-82-4

1-Hexadecanol

~98%

hexadecoxy(trimethyl)silane Structure

6221-90-5

hexadecoxy(trim...

(3-phenyl-prop-2-en-1-oxy)trimethylsilane Structure

109283-53-6

(3-phenyl-prop-...

~98%

Cinnamyl alcohol Structure

104-54-1

Cinnamyl alcohol

tert-butyl-dimethyl-(3-phenylprop-2-enoxy)silane Structure

71700-50-0

tert-butyl-dime...

~99%

Cinnamyl alcohol Structure

104-54-1

Cinnamyl alcohol

4-MeOPhCH2OSi(Me)2t-Bu Structure

101803-60-5

4-MeOPhCH2OSi(M...

~99%

4-Methoxybenzyl alcohol Structure

105-13-5

4-Methoxybenzyl...

(4-Methoxybenzyl)(trimethylsilyl) ether Structure

14629-56-2

(4-Methoxybenzy...

~99%

4-Methoxybenzyl alcohol Structure

105-13-5

4-Methoxybenzyl...

Bornyl-endo-OTMS Structure

37555-29-6

Bornyl-endo-OTMS

~99%

DL-2-Bornanol Structure

6627-72-1

DL-2-Bornanol

docosoxy(trimethyl)silane Structure

42449-18-3

docosoxy(trimet...

~98%

1-Docosanol Structure

661-19-8

1-Docosanol

tert-butyldimethyl(2,2,2-trichloroethoxy)silane Structure

86379-25-1

tert-butyldimet...

~97%

Ethapon Structure

115-20-8

Ethapon

trimethyl[5-methyl-2-(1-methylethyl)cyclohexyloxy]silane Structure

62338-23-2

trimethyl[5-met...

~98%

Menthol Structure

89-78-1

Menthol

trimethyl(2,2,2-trichloroethoxy)silane Structure

41262-38-8

trimethyl(2,2,2...

~99%

Ethapon Structure

115-20-8

Ethapon

2-{[(tert-butyl)dimethylsilyl]oxy}-4-methyl-1-(1-methylethyl)cyclohexane Structure

129368-71-4

2-{[(tert-butyl...

~99%

Menthol Structure

89-78-1

Menthol

(α-Methylbenzyl)(trimethylsilyl) ether Structure

14856-75-8

(α-Methylbenzyl...

~99%

Methylbenzylalcohol Structure

98-85-1

Methylbenzylalcohol

tert-butyl-dimethyl-(1-phenylethoxy)silane Structure

92976-56-2

tert-butyl-dime...

~99%

Methylbenzylalcohol Structure

98-85-1

Methylbenzylalcohol


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