Journal of Molecular Catalysis A: Chemical

Titanium silicates as efficient catalyst for alkylation and acylation of silyl enol ethers under liquid-phase conditions

M Sasidharan, A Bhaumik

Index: Sasidharan, Manickam; Bhaumik, Asim Journal of Molecular Catalysis A: Chemical, 2011 , vol. 346, # 1-2 p. 87 - 93

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Citation Number: 2

Abstract

The activity of titanium-and tin-silicate samples such as TS-1, TS-2, Ti-β and Sn-MFI has been investigated for acylation and alkylation of silyl enol ethers under mild liquid-phase conditions. Silyl enol ethers successfully react with acetyl chloride and tert-butyl chloride under dry conditions in the presence of above catalysts to produce the corresponding acylated and alkylated products, respectively. In the case of acetylation reaction, two ...