The Journal of Organic Chemistry

Catalytic double bond isomerization by polystyrene-anchored dichlorotris (triphenylphosphine) ruthenium

A Zoran, Y Sasson, J Blum

Index: Zoran, Amikam; Sasson, Yoel; Blum, Jochanan Journal of Organic Chemistry, 1981 , vol. 46, # 2 p. 255 - 260

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Citation Number: 48

Abstract

Dichlorotris (tripheny1phosphine) ruthenium has been anchored to diphenylphosphinatsd styrene-divhylbenzene copolymer. The resulting leaching-resistant catalyst was employed succesefully for the isomerization of dlylbenzenes and allyl alcohols in numerous turnovers. The stability of the catalyst was examined in different media, and its performances were compared with those of homogeneous RuC12 (PPh& and with those of polymer-bound as ...

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