The use of sublimable chlorotricarbonyl bis (phenylimino) acenaphthene rhenium (I) complexes as photosensitizers in bulk-heterojunction photovoltaic devices

…, QY Leung, WY Tam, WK Chan, AB Djurišić

Index: Mak, Chris S.K.; Wong, Hei Ling; Leung, Qing Yun; Tam, Wing Yan; Chan, Wai Kin; Djurisic, Aleksandra B. Journal of Organometallic Chemistry, 2009 , vol. 694, # 17 p. 2770 - 2776

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Citation Number: 32

Abstract

A series of sublimable substituted chlorotricarbonyl bis (phenylimino) acenaphthene rhenium (I) complexes was synthesized and used in the fabrication of photovoltaic devices. The hole and electron carrier mobilities of these complexes are in the order of 10− 3 to 10− 4cm2V− 1s− 1. Heterojunction devices with CuPc/complex/C60 (CuPc= copper phthalocyanine) as the active layer and bulk heterojunction devices with complex: C60 as ...