Bis (aryl) acenaphthenequinonediimine Substituent Effect on the Properties and Coordination Environment of Ligands and Their Bis??Chelate AgI Complexes

PA Papanikolaou, M Gdaniec, B Wicher…

Index: Papanikolaou, Panagiotis A.; Gdaniec, Maria; Wicher, Barbara; Akrivos, Pericles D.; Tkachenko, Nikolai V. European Journal of Inorganic Chemistry, 2013 , # 29 p. 5196 - 5205

Full Text: HTML

Citation Number: 1

Abstract

Abstract The reaction of a series of Ar–BIAN ligands (Ar= o-Ph, m-Cl, m-CF 3, p-Cl, p-MeO, and p-Me–C 6 H 4) with AgNO 3 results in the formation of the corresponding bis-chelate complexes. Substituent groups on the aryl rings seem to offer tunability of the electronic properties of the diimines, also affecting the metal coordination environment through the mono-coordination or chelation of the nitrate anion as promoted by the substituents p- ...