Metal-catalyzed rearrangement of cyclopropenes to allenes

J Li, C Sun, S Demerzhan, D Lee

Index: Sun, Chunrui; Li, Jingwei; Demerzhan, Silviya; Lee, Daesung Arkivoc, 2011 , vol. 2011, # 4 p. 17 - 25

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Citation Number: 22

Abstract

The relatively facile preparation and better reaction profiles of non-C3-substituted silylated cyclopropenes relative to other cyclopropenes prompted us to choose them as the substrate platform for further exploration of the rearrangement of cyclopropenes to allenes. These non-C3-substituted cyclopropenes

~66%

Selective formation of alkenes from trimethylsilylmethyl ket...

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