Nickel??Catalyzed Direct C H Arylation and Alkenylation of Heteroarenes with Organosilicon Reagents

H Hachiya, K Hirano, T Satoh…

Index: Hachiya, Hitoshi; Hirano, Koji; Satoh, Tetsuya; Miura, Masahiro Angewandte Chemie - International Edition, 2010 , vol. 49, # 12 p. 2202 - 2205

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Citation Number: 163

Abstract

Organosilicon compounds are useful and ubiquitous synthetic reagents in modern organic chemistry. Among the versatile transformations involving them, transition metal catalyzed cross-coupling reactions of organic halides or pseudohalides, that is Hiyama cross-coupling, ranks as one of the most powerful and reliable CÀC bond-forming reactions in organic synthesis.[1] Recent efforts by Nakao, Hiyama, and co-workers,[2] and Denmark et al.[3] ...