RSC Advances

One-pot synthesis of symmetric 1, 7-dicarbonyl compounds via a tandem radical addition–elimination–addition reaction

Z Huang, J Xu

Index: Huang, Zhongyan; Xu, Jiaxi RSC Advances, 2013 , vol. 3, # 35 p. 15114 - 15120

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Abstract

A novel approach to synthesize symmetric 1, 7-dicarbonyl compounds via a tandem radical addition–elimination–addition reaction of S-carbonylmethyl xanthates with allylmethylsulfone and its analogues has been developed. Radicals were produced from S-