Homolytic displacement at saturated carbon. Part 9. The reactions of trichloromethanesulfonyl chloride with pent-4-enylcobaloximes and with olefins. A novel route to ( …

…, P Bougeard, A Bury, CJ Cooksey…

Index: Ashcroft, Martyn M.; Bougeard, Peter; Bury, Adrian; Cooksey, Christopher J.; Johnson, Michael D.; et al. Journal of Organic Chemistry, 1984 , vol. 49, # 10 p. 1751 - 1761

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Citation Number: 16

Abstract

Pent-4-enylcobaloximes react with trichloromethanesulfonyl chloride in inert solvents under irradiation with tungsten lamps to give good yields of 2-(~,~,~-trichloroethyl) sulfolanes. The same products are formed in the thermal reactions in the presence of an excess of sulfur dioxide. Studies of the reactions of related olefins with trichloromethanesulfonyl chloride catalyzed by the photolysis of secondary organombaloximes under mild conditions show ...