Homolytic displacement at saturated carbon. Part 9. The reactions of trichloromethanesulfonyl chloride with pent-4-enylcobaloximes and with olefins. A novel route to ( …

…, P Bougeard, A Bury, CJ Cooksey…

文献索引：Ashcroft, Martyn M.; Bougeard, Peter; Bury, Adrian; Cooksey, Christopher J.; Johnson, Michael D.; et al. Journal of Organic Chemistry, 1984 , vol. 49, # 10 p. 1751 - 1761

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被引用次数: 16

摘要

Pent-4-enylcobaloximes react with trichloromethanesulfonyl chloride in inert solvents under irradiation with tungsten lamps to give good yields of 2-(~,~,~-trichloroethyl) sulfolanes. The same products are formed in the thermal reactions in the presence of an excess of sulfur dioxide. Studies of the reactions of related olefins with trichloromethanesulfonyl chloride catalyzed by the photolysis of secondary organombaloximes under mild conditions show ...