Effect of solvent on. beta.-arylalkyl solvolysis

FL Schadt III, CJ Lancelot…

Index: Schadt,F.L. et al. Journal of the American Chemical Society, 1978 , vol. 100, p. 228 - 246

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Citation Number: 52

Abstract

Abstract: Solvolysis rate constants, k,, for a series of (3-arylethyl and 1-aryl-2-propyl tosylates in solvents ranging from EtOH to CF3C02H were dissected into their aryl assisted (Fka) and aryl unassisted (k,) components in order to determine the effect of solvent on each reaction pathway. Correlations of k, and ka for PhCH2CHzOTs and PhCH2CH (OTs) CH3, and of kt for appropriate model substrates, EtOTs and 2-PrOTs, by the full Winstein-Grunwald ...