Inorganica chimica acta

Synthesis and 119Sn mössbauer spectroscopic studies of inorganic tin (IV) halide and mixed halide/pseudohalide complexes with n-donor ligands

PA Cusack, BN Patel

Index: Cusack, Paul A.; Patel, Bhagwati N. Inorganica Chimica Acta, 1984 , vol. 86, p. 1 - 4

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Citation Number: 5

Abstract

Abstract A series of tin (IV) halide and tin (IV) halide isothiocyanate adducts of nitrogen- donor ligands, of general formulae, X n Sn (NCS) 4− n· L 2,(n= 2− 4), have been synthesized and studied by 119 Sn Mössbauer spectroscopy. The complexes all show single Mössbauer resonances and their isomer shift values are found to be a linear function of the average Mulliken electronegativities of the halide/isothiocyanate ligands around the tin atom.