Ruthenium complex catalyzed intermolecular hydroacylation and transhydroformylation of olefins with aldehydes

…, M Akazome, Y Tsuji, Y Watanabe

Index: Kondo, Teruyuki; Akazome, Motohiro; Tsuji, Yasushi; Watanabe, Yoshihisa Journal of Organic Chemistry, 1990 , vol. 55, # 4 p. 1286 - 1291

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Citation Number: 150

Abstract

Low-valent ruthenium complexes such as dodecacarbonyltriruthenium (RU~(CO)~~),(~ 4-1, 5-cyclooctadiene)(qe-l, 3, 5-cyclooctatriene) ruthenium (Ru (C0D)(COT)) and bis (q6- cyclooctadieny1) ruthenium showed high catalytic activity for the intermolecular hydroacylation of olefiis with various aromatic and heteroaromatic aldehydes at 180-200" C for 24-48 h under an initial carbon monoxide pressure of 20 kg cm-2 to give unsymmetric ...