甲乙酮

常用名 甲乙酮 英文名 butan-2-one
CAS号 78-93-3 分子量 72.106
密度 0.8±0.1 g/cm3 沸点 75.6±3.0 °C at 760 mmHg
分子式 C4H8O 熔点 -87 °C
MSDS甲乙酮的MSDS|SDS|pdf下载 中文版 美版

管制品

闪点 -3.3±0.0 °C
符号 GHS02 GHS07
GHS02, GHS07
信号词 Danger

 甲乙酮用途


1.丁酮主要用作溶剂,如用于润滑油脱蜡、涂料工业及多种树脂溶剂、植物油的萃取过程及精制过程的共沸精馏,其优点是溶解性强,挥发性比丙酮低,属中沸点酮类溶剂。

2.丁酮还是制备医药、染料、洗涤剂、香料、抗氧化剂以及某些催化剂的是中间体,合成抗脱皮剂甲基乙基酮肟、聚合催化剂甲基乙基酮过氧化物、阻蚀剂甲基戊炔醇等,在电子工业中用作集成电路光刻后的显影剂。

3.用作洗涤剂、润滑油脱蜡剂、硫化促进剂和反应中间体等。

4.用于有机合成。用作色谱分析标准物质、溶剂。

5.用于电子工业,常用作清洗去油剂。

6.除了广泛用于炼油、涂料、助剂、胶黏剂、染料、医药及电子元件清洗等方面外,主要用于硝酸纤维素、乙烯基树脂、丙烯酸树脂和其他合成树脂的溶剂。其优点是溶解性强,挥发性比丙酮低。在植物油的萃取、精制过程的共沸精馏以及制备香料、抗氧化剂等方面也有应用。

7.是有机合成原料,可作溶剂。在炼油工业中作润滑油的脱蜡剂,同时用于医药、涂料、染料、洗涤剂、香料和电子等工业。液体油墨的溶剂。化妆品中用于指甲油的制造,作为低沸点溶剂,能降低指甲油的黏度,有快干性。

8.用作溶剂、脱蜡剂,也用于有机合成,及作为合成香料和医药的原料。

更多

 甲乙酮物理化学性质

[ 密度 ]: 0.8±0.1 g/cm3
[ 沸点 ]: 75.6±3.0 °C at 760 mmHg
[ 熔点 ]: -87 °C
[ 分子式 ]: C4H8O
[ 分子量 ]: 72.106
[ 闪点 ]: -3.3±0.0 °C
[ 精确质量 ]: 72.057518
[ PSA ]: 17.07000
[ LogP ]: 0.37
[ 外观性状 ]: 无色液体,有似丙酮的气味。
[ 蒸汽密度 ]: 2.49 (vs air)
[ 蒸汽压 ]: 114.5±0.1 mmHg at 25°C
[ 折射率 ]: 1.367
[ 储存条件 ]:

储存注意事项储存于阴凉、通风的库房。远离火种、热源。库温不宜超过37℃。保持容器密封。应与氧化剂、还原剂、碱类分开存放,切忌混储。采用防爆型照明、通风设施。禁止使用易产生火花的机械设备和工具。储区应备有泄漏应急处理设备和合适的收容材料。

[ 稳定性 ]:

1.化学性质:丁酮由于具有羰基及与羰基相邻接的活泼氢,因此容易发生各种反应。与盐酸或氢氧化钠一起加热发生缩合,生成3,4-二甲基-3-己烯-2-酮或3-甲基-3-庚烯-5-酮。长时间受日光照射时,生成乙烷、乙酸、缩合产物等。用硝酸氧化时生成联乙酰。用铬酸等强氧化剂氧化时生成乙酸。丁酮对热比较稳定,500℃以上热裂生成烯酮或甲基烯酮。与脂肪族或芳香族醛发生缩合时,生成高分子量的酮、环状化合物、缩酮以及树脂等。例如与甲醛在氢氧化钠存在下缩合,首先生成2-甲基-1-丁醇-3-酮,接着脱水生成甲基异丙烯基酮。该化合物受日光或紫外光照射时发生树脂化。与苯酚缩合生成2,2-双(4-羟基苯基)丁烷。与脂肪族酯在碱性催化剂存在下反应,生成β-二酮。在酸性催化剂存在下与酸酐作用发生酰化反应,生成β-二酮。与氰化氢反应生成氰醇。与氨反应生成酮基哌啶衍生物。丁酮的α-氢原子容易被卤素取代生成各种卤代酮,例如与氯作用生成3-氯-2-丁酮。与2,4-二硝基苯肼作用生成黄色的2,4-二硝基苯腙(m.p. 115℃)。

2.稳定性 稳定

3.禁配物 强氧化剂、碱类、强还原剂

4.聚合危害 不聚合

[ 水溶解性 ]: 290 g/L (20 ºC)
[ 分子结构 ]:

1、摩尔折射率:20.60

2、摩尔体积(cm3/mol):91.6

3、等张比容(90.2K):196.3

4、表面张力(dyne/cm):21.0

5、极化率(10-24cm3):8.17

[ 计算化学 ]:

1.疏水参数计算参考值(XlogP):无

2.氢键供体数量:0

3.氢键受体数量:1

4.可旋转化学键数量:1

5.互变异构体数量:3

6.拓扑分子极性表面积17.1

7.重原子数量:5

8.表面电荷:0

9.复杂度:38.9

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:1

[ 更多 ]:

1.性状:无色液体,有似丙酮的气味。

2.熔点(℃):-85.9

3.沸点(℃):79.6

4.相对密度(水=1):0.81

5.相对蒸气密度(空气=1):2.42

6.饱和蒸气压(kPa):10.5(20℃)

7.燃烧热(kJ/mol):-2261.7

8.临界温度(℃):262.5

9.临界压力(MPa):4.15

10.辛醇/水分配系数:0.29

11.闪点(℃):-9(CC)

12.引燃温度(℃):404

13.爆炸上限(%):11.5

14.爆炸下限(%):1.8

15.溶解性:溶于水、乙醇、乙醚、丙酮、苯,可混溶于油类。

16.相对密度(g/mL,20/4ºC):0.8049

17.相对密度(g/mL,25/4ºC):0.7997

18.折射率(n20ºC):1.3788

19.折射率(n25ºC):1.3764

20.黏度(mPa·s,25ºC):0.423

21.黏度(mPa·s,30ºC):0.365

22.闪点(ºC,闭口):-7.2

23.闪点(ºC,开口):1.67

24.燃点(ºC):516

25.蒸发热(J/mol,b.p.):23.3

26.熔化热(KJ/mol):8.4

27.生成热(KJ/mol):279.2

28.比热容(KJ/(kg·K),定压):2.297

29.电导率(S/m):3.6×10-9

30.体膨胀系数(K-1,0~80ºC):0.00142

31.体膨胀系数(K-1,0~30ºC):0.00129

32.临界密度(g/mL):0.270

33.临界体积(cm3·mol-1):267

34.临界压缩因子:0.252

35.偏心因子:0.324

36.Lennard-Jones参数(A):14.49

37.Lennard-Jones参数(K):145.9

38.溶度参数(J·cm-3)0.5:18.796

39.van der Waals面积(cm2·mol-1):7.910×109

40.van der Waals体积(cm3·mol-1):49.270

41.气相标准燃烧热(焓)(kJ·mol-1):-2478.6

42.气相标准声称热(焓)( kJ·mol-1) :-238.7

43.气相标准熵(J·mol-1·K-1) :339.47

44.气相标准生成自由能( kJ·mol-1):-146.6

45.气相标准热熔(J·mol-1·K-1):103.26

46.液相标准燃烧热(焓)(kJ·mol-1):-2444.1

47.液相标准声称热(焓)( kJ·mol-1):-273.3

48.液相标准熵(J·mol-1·K-1) :239.0

49.液相标准生成自由能( kJ·mol-1):-151.4

50.液相标准热熔(J·mol-1·K-1):158.9

 甲乙酮MSDS


模块1. 化学品
1.1 产品标识符
: 2-丁酮
产品名称
1.2 鉴别的其他方法
Methyl ethyl ketone
MEK
Ethyl methyl ketone
1.3 有关的确定了的物质或混合物的用途和建议不适合的用途
仅用于研发。不作为药品、家庭或其它用途。

模块2. 危险性概述

模块16. 其他信息
进一步信息
上述信息视为正确,但不包含所有的信息,仅作为指引使用。本文件中的信息是基于我们目前所知,就正
确的安全提示来说适用于本品。该信息不代表对此产品性质的保证。
参见发票或包装条的反面。
2.1 GHS分类
易燃液体 (类别 2)
急性毒性, 经口 (类别 5)
急性毒性, 吸入 (类别 5)
严重眼睛损伤/眼睛刺激性 (类别 2A)
特异性靶器官系统毒性(一次接触) (类别 3), 中枢神经系统
2.2 GHS 标记要素,包括预防性的陈述
象形图
警示词危险
危险申明
H225高度易燃液体和蒸气。
H303 + H333吞咽或吸入可能有害。
H319造成严重眼刺激。
H336可能造成昏昏欲睡或眩晕。
警告申明
预防措施
P210远离热源/火花/明火。禁止吸烟。
P233保持容器密闭。
P240容器和装载设备接地/等势联接。
P241使用防爆的电气/通风/照明设备。
P242只能使用不产生火花的工具。
P243采取防止静电放电的措施。
P261避免吸入粉尘/烟/气体/烟雾/蒸气/喷雾。
P264操作后彻底清洗皮肤。
P271只能在室外或通风良好之处使用。
P280戴防护手套/戴防护眼罩/戴防护面具。
事故响应
P303 + P361 + P353如果皮肤(或头发)接触:立即除去∕脱掉所有沾污的衣物。用水清洗皮肤∕
淋浴。
P304 + P340 + P312如果吸入:将受害人移至空气新鲜处并保持呼吸舒适的姿势休息。
如觉不适,呼叫解毒中心或就医。
P305 + P351 + P338如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出
隐形眼镜。继续冲洗。
P312如感觉不适,呼叫解毒中心或医生。
P337 + P313如仍觉眼刺激:求医/就诊。
P370 + P378在发生火灾时:用干砂,干粉或抗溶性泡沫扑灭。
储存
P403 + P233存放在通风良好的地方。保持容器密闭。
P403 + P235存放在通风良好的地方。保持低温。
P405存放处须加锁。
废弃处置
P501将内装物/容器送到批准的废物处理厂处理。
2.3 其它危害物
反复暴露可能引起皮肤干燥和开裂。

模块3. 成分/组成信息
3.1 物 质
: Methyl ethyl ketone
别名
MEK
Ethyl methyl ketone
: C4H8O
分子式
: 72.11 g/mol
分子量
组分浓度或浓度范围
Ethyl methyl ketone
化学文摘登记号(CAS78-93-3<= 100 %
No.)201-159-0
EC-编号606-002-00-3
索引编号

模块4. 急救措施
4.1 必要的急救措施描述
一般的建议
请教医生。 向到现场的医生出示此安全技术说明书。
吸入
如果吸入,请将患者移到新鲜空气处。 如呼吸停止,进行人工呼吸。 请教医生。
皮肤接触
用肥皂和大量的水冲洗。 请教医生。
眼睛接触
用大量水彻底冲洗至少15分钟并请教医生。
食入
禁止催吐。 切勿给失去知觉者喂食任何东西。 用水漱口。 请教医生。
4.2 主要症状和影响,急性和迟发效应
中枢神经系统抑制, 胃肠道功能紊乱, 麻醉
4.3 及时的医疗处理和所需的特殊处理的说明和指示
无数据资料

模块5. 消防措施
5.1 灭火介质
灭火方法及灭火剂
用水雾,耐醇泡沫,干粉或二氧化碳灭火。
5.2 源于此物质或混合物的特别的危害
无数据资料
5.3 给消防员的建议
如有必要,佩戴自给式呼吸器进行消防作业。
5.4 进一步信息
喷水冷却未打开的容器。

模块6. 泄露应急处理
6.1 作业人员防护措施、防护装备和应急处置程序
使用个人防护装备。 避免吸入蒸气、气雾或气体。 保证充分的通风。 消除所有火源。
将人员疏散到安全区域。 注意蒸气积累达到可爆炸的浓度,蒸气可蓄积在地面低洼处。
6.2 环境保护措施
如能确保安全,可采取措施防止进一步的泄漏或溢出。 不要让产品进入下水道。
6.3 泄漏化学品的收容、清除方法及所使用的处置材料
围堵溢出,用防电真空清洁器或湿刷子将溢出物收集起来,并放置到容器中去,根据当地规定处理(见第13部
分)。
6.4 参考其他部分
丢弃处理请参阅第13节。

模块7. 操作处置与储存
7.1 安全操作的注意事项
避免接触皮肤和眼睛。 避免吸入蒸气或雾滴。
切勿靠近火源。-严禁烟火。采取措施防止静电积聚。
7.2 安全储存的条件,包括任何不兼容性
充气保存 贮存在阴凉处。 使容器保持密闭,储存在干燥通风处。
打开了的容器必须仔细重新封口并保持竖放位置以防止泄漏。
吸湿的.
7.3 特定用途
无数据资料

模块8. 接触控制和个体防护
8.1 控制参数
职业接触限值
组分化学文摘登值控制参数依据
记号(CAS
No.)
Ethyl methyl ketone78-93-3PC-300 mg/m3工作场所有害因素职业接触限值 -
TWA化学有害因素
PC-600 mg/m3工作场所有害因素职业接触限值 -
STEL化学有害因素
8.2 暴露控制
适当的技术控制
按照良好的工业卫生和安全规范进行操作。 休息前及工作结束时洗手。
个体防护装备
眼面防护
面罩與安全眼鏡请使用经官方标准如NIOSH (美国) 或 EN 166(欧盟) 检测与批准的设备防护眼部。
皮肤保护
戴手套取 手套在使用前必须受检查。
请使用合适的方法脱除手套(不要接触手套外部表面),避免任何皮肤部位接触此产品.
使用后请将被污染过的手套根据相关法律法规和有效的实验室规章程序谨慎处理. 请清洗并吹干双手
所选择的保护手套必须符合EU的89/686/EEC规定和从它衍生出来的EN 376标准。
飞溅保护
材料: 丁基橡胶
最小的层厚度 0.3 mm
溶剂渗透时间: 292 min
测试过的物质Butoject® (KCL 897 / Z677647, 规格 M)
, 测试方法 EN374
如果以溶剂形式应用或与其它物质混合应用,或在不同于EN
374规定的条件下应用,请与EC批准的手套的供应商联系。
这个推荐只是建议性的,并且务必让熟悉我们客户计划使用的特定情况的工业卫生学专家评估确认才可.
这不应该解释为在提供对任何特定使用情况方法的批准.
身体保护
防渗透的衣服, 阻燃防静电防护服。,
防护设备的类型必须根据特定工作场所中的危险物的浓度和数量来选择。
呼吸系统防护
如危险性评测显示需要使用空气净化的防毒面具,请使用全面罩式多功能防毒面具(US)或ABEK型
(EN
14387)防毒面具筒作为工程控制的候补。如果防毒面具是保护的唯一方式,则使用全面罩式送风防
毒面具。 呼吸器使用经过测试并通过政府标准如NIOSH(US)或CEN(EU)的呼吸器和零件。

模块9. 理化特性
9.1 基本的理化特性的信息
a) 外观与性状
形状: 液体, 澄清
颜色: 无色
b) 气味
无数据资料
c) 气味阈值
无数据资料
d) pH值
无数据资料
e) 熔点/凝固点
熔点/熔点范围: -87 °C
f) 初沸点和沸程
80 °C
g) 闪点
-2.99 °C - 闭杯
h) 蒸发速率
无数据资料
i) 易燃性(固体,气体)
无数据资料
j) 高的/低的燃烧性或爆炸性限度 爆炸上限: 10.1 %(V)
爆炸下限: 1.8 %(V)
k) 蒸气压
95 hPa 在 20 °C
l) 蒸气密度
2.49 - (空气= 1.0)
m) 密度/相对密度
0.805 g/mL 在 25 °C
n) 水溶性
可溶
o) 正辛醇/水分配系数
log Pow: 0.29
p) 自燃温度
无数据资料
q) 分解温度
无数据资料
r) 黏度
无数据资料

模块10. 稳定性和反应活性
10.1 反应性
无数据资料
10.2 稳定性
无数据资料
10.3 危险反应
无数据资料
10.4 应避免的条件
暴露在潮湿中。
热、火焰和火花。
10.5 不相容的物质
氧化剂, 强还原剂
10.6 危险的分解产物
其它分解产物 - 无数据资料

模块11. 毒理学资料
11.1 毒理学影响的信息
急性毒性
LD50 经口 - 大鼠 - 2,737 mg/kg
LC50 吸入 - 小鼠 - 4 h - 32,000 mg/m3
LC50 吸入 - 哺乳动物的 - 38,000 mg/m3
LD50 经皮 - 家兔 - 6,480 mg/kg
皮肤腐蚀/刺激
皮肤 - 家兔 - 无皮肤刺激 - OECD测试导则404
严重眼睛损伤/眼刺激
眼睛 - 家兔 - 刺激眼睛。 - OECD测试导则405
呼吸或皮肤过敏
无数据资料
生殖细胞致突变性
无数据资料
致癌性
IARC:
此产品中没有大于或等于 0。1%含量的组分被 IARC鉴别为可能的或肯定的人类致癌物。
生殖毒性
无数据资料
特异性靶器官系统毒性(一次接触)
可能造成昏昏欲睡或眩晕。
特异性靶器官系统毒性(反复接触)
无数据资料
吸入危害
无数据资料
潜在的健康影响
吸入吸入可能有害。 可能引起呼吸道刺激。 蒸气可引起睡意和眩昏。
食入吞咽可能有害。
皮肤通过皮肤吸收可能有害。 可能引起皮肤刺激。
眼睛造成严重眼刺激。
接触后的征兆和症状
中枢神经系统抑制, 胃肠道功能紊乱, 麻醉
附加说明
化学物质毒性作用登记: EL6475000

模块12. 生态学资料
12.1 生态毒性
对鱼类的毒性死亡率 NOEC - Cyprinodon variegatus (红鲈) - 400 mg/l - 96 h
LC50 - Pimephales promelas (肥头鲦鱼) - 3,130 - 3,320 mg/l - 96 h
对水溞和其他水生无脊LC50 - Daphnia magna (水溞) - > 520 mg/l - 48 h
椎动物的毒性
EC50 - Daphnia magna (水溞) - 7,060 mg/l - 24 h
12.2 持久性和降解性
无数据资料
12.3 潜在的生物累积性
无数据资料
12.4 土壤中的迁移性
无数据资料
12.5 PBT和vPvB的结果评价
无数据资料
12.6 其他不良影响
无数据资料

模块13. 废弃处置
13.1 废物处理方法
产品
在装备有加力燃烧室和洗刷设备的化学焚烧炉内燃烧处理,特别在点燃的时候要注意,因为此物质是高度易燃
性物质 将剩余的和不可回收的溶液交给有许可证的公司处理。
受污染的容器和包装
按未用产品处置。

模块14. 运输信息
14.1 联合国编号
欧洲陆运危规: 1193国际海运危规: 1193国际空运危规: 1193
14.2 联合国运输名称
欧洲陆运危规: ETHYL METHYL KETONE
国际海运危规: ETHYL METHYL KETONE
国际空运危规: Ethyl methyl ketone
14.3 运输危险类别
欧洲陆运危规: 3国际海运危规: 3国际空运危规: 3
14.4 包裹组
欧洲陆运危规: II国际海运危规: II国际空运危规: II
14.5 环境危险
欧洲陆运危规: 否国际海运危规国际空运危规: 否
海洋污染物(是/否): 否
14.6 特殊防范措施
无数据资料


模块 15 - 法规信息
N/A

 甲乙酮毒性和生态

甲乙酮毒理学数据:

1.急性毒性

LD50:2737mg/kg(大鼠经口);6480mg/kg(兔经皮)

LC50:23500mg/m3(大鼠吸入,8h)

2.刺激性

家兔经皮:13780μg(24h),轻度刺激(开放性刺激试验)

家兔经眼:80mg,引起刺激。

3.亚急性与慢性毒性 大鼠暴露于5000ppm,每天6h,每周5d,共90d。引起雄性大鼠肝重增加,脑和脾重量下降,血液生化指标轻度变化;雄性大鼠仅轻度肝重增加。

4.致突变性 性染色体缺失和不分离:酿酒酵母菌33800ppm。

5.致畸性 大鼠孕后6~15d吸入最低中毒剂量(TCLo)3000ppm/7h,致颅面部(包括鼻、舌)、泌尿生殖系统发育畸形。大鼠孕后6~10d吸入最低中毒剂量(TCLo)2900mg/m3,致颅面部(包括鼻、舌)、肌肉骨骼系统、胃肠道发育畸形。

6.其他 大鼠吸入最低中毒浓度(TCLo):3000ppm(7h)(孕6~15d),致颅面部(包括鼻、舌)发育异常,致泌尿生殖系统发育异常,致凝血异常。

TCLo:100ppm(人吸入,5min)

甲乙酮生态学数据:

1.生态毒性

LC50:1690~5640mg/L(96h)(蓝鳃太阳鱼);3200mg/L(96h)(黑头呆鱼,pH值7.5);1950mg/L(24h)(卤虫);<520mg/L(48h)(水蚤,pH值8);918~3349mg/L(48h)(水蚤,pH值7.21)

IC50:110~4300mg/L(72h)(藻类)

2.生物降解性

好氧生物降解(h):24~168

厌氧生物降解(h):96~672

3.非生物降解性

水中光氧化半衰期(h):1.80×104~7.10×105

空气中光氧化半衰期(h):64.2~642

一级水解半衰期(h):>50a

CHEMICAL IDENTIFICATION

RTECS NUMBER :
EL6475000
CHEMICAL NAME :
2-Butanone
CAS REGISTRY NUMBER :
78-93-3
LAST UPDATED :
199712
DATA ITEMS CITED :
64
MOLECULAR FORMULA :
C4-H8-O
MOLECULAR WEIGHT :
72.12
WISWESSER LINE NOTATION :
2V1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Human
TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
TYPE OF TEST :
Open irritation test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
TYPE OF TEST :
TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Human
DOSE/DURATION :
100 ppm/5M
TOXIC EFFECTS :
Sense Organs and Special Senses (Olfaction) - effect, not otherwise specified Sense Organs and Special Senses (Eye) - conjunctive irritation Lungs, Thorax, or Respiration - other changes
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
2737 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
23500 mg/m3/8H
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
607 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
4050 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
32 gm/m3/4H
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
616 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
6480 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - guinea pig
DOSE/DURATION :
2 gm/kg
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Mammal - species unspecified
DOSE/DURATION :
38 gm/m3
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
5000 ppm/6H/90D-I
TOXIC EFFECTS :
Liver - changes in liver weight Kidney, Ureter, Bladder - urine volume increased Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - transaminases
TYPE OF TEST :
TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
750 ppm/7H/7D-I
TOXIC EFFECTS :
Liver - liver function tests impaired
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Subcutaneous
SPECIES OBSERVED :
Mammal - cat
DOSE/DURATION :
55500 mg/kg/37W-I
TOXIC EFFECTS :
Related to Chronic Data - death
TYPE OF TEST :
TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE :
Inhalation
DOSE :
3000 ppm/7H
SEX/DURATION :
female 6-15 day(s) after conception
TOXIC EFFECTS :
Reproductive - Specific Developmental Abnormalities - craniofacial (including nose and tongue) Reproductive - Specific Developmental Abnormalities - urogenital system Reproductive - Specific Developmental Abnormalities - homeostasis
TYPE OF TEST :
TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE :
Inhalation
DOSE :
1000 ppm/7H
SEX/DURATION :
female 6-15 day(s) after conception
TOXIC EFFECTS :
Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death, e.g., stunted fetus) Reproductive - Specific Developmental Abnormalities - musculoskeletal system
TYPE OF TEST :
TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE :
Inhalation
DOSE :
3000 ppm/7H
SEX/DURATION :
female 6-15 day(s) after conception
TOXIC EFFECTS :
Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death, e.g., stunted fetus)

MUTATION DATA

TYPE OF TEST :
Sex chromosome loss and nondisjunction
TEST SYSTEM :
Yeast - Saccharomyces cerevisiae
REFERENCE :
MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 149,339,1985 *** REVIEWS *** ACGIH TLV-STEL 885 mg/m3 (300 ppm) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 ACGIH TLV-TWA 590 mg/m3 (200 ppm) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 TOXICOLOGY REVIEW ECIET* European Chemical Industry Ecology and Toxicology Centre. Joint Assessment of Commodity Chemicals. (Avenue Louise 250, B-63, B-1050 Brussels, Belgium) Volume(issue)/page/year: (3),-,1983 TOXICOLOGY REVIEW NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: DE89-563 *** U.S. STANDARDS AND REGULATIONS *** EPA FIFRA 1988 PESTICIDE SUBJECT TO REGISTRATION OR RE-REGISTRATION FEREAC Federal Register. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) V.1- 1936- Volume(issue)/page/year: 54,7740,1989 MSHA STANDARD-air:TWA 200 ppm (590 mg/m3) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,29,1971 OSHA PEL (Gen Indu):8H TWA 200 ppm (590 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 200 ppm (590 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 200 ppm (590 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 200 ppm (590 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 150 ppm (445 mg/m3);STEL 300 ppm (890 mg/m3) JAN 1993 OEL-AUSTRIA:TWA 200 ppm (590 mg/m3) JAN 1993 OEL-BELGIUM:TWA 200 ppm (590 mg/m3);STEL 300 ppm (885 mg/m3) JAN 1993 OEL-DENMARK:TWA 100 ppm (290 mg/m3);Skin JAN 1993 OEL-FINLAND:TWA 150 ppm (440 mg/m3);STEL 190 ppm;Skin JAN 1993 OEL-FRANCE:TWA 200 ppm (600 mg/m3);Skin JAN 1993 OEL-GERMANY:TWA 200 ppm (590 mg/m3) JAN 1993 OEL-HUNGARY:TWA 200 mg/m3;STEL 600 mg/m3 JAN 1993 OEL-INDIA:TWA 200 ppm (590 mg/m3);STEL 300 ppm (885 mg/m3) JAN 1993 OEL-JAPAN:TWA 200 ppm (590 mg/m3) JAN 1993 OEL-THE NETHERLANDS:TWA 200 ppm (590 mg/m3) JAN 1993 OEL-THE PHILIPPINES:TWA 200 ppm (590 mg/m3) JAN 1993 OEL-POLAND:TWA 200 mg/m3 JAN 1993 OEL-RUSSIA:TWA 200 ppm;STEL 200 mg/m3 JAN 1993 OEL-SWEDEN:TWA 50 ppm (150 mg/m3);STEL 100 ppm (300 mg/m3) JAN 1993 OEL-SWITZERLAND:TWA 200 ppm (590 mg/m3);STEL 400 ppmJAN 1993 OEL-TURKEY:TWA 200 ppm (590 mg/m3) JAN 1993 OEL-UNITED KINGDOM:TWA 200 ppm (590 mg/m3);STEL 300 ppm JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO METHYL ETHYL KETONE-air:10H TWA 200 ppm;STEL 300 ppm REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992 NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 13980 No. of Facilities: 64013 (estimated) No. of Industries: 319 No. of Occupations: 177 No. of Employees: 801382 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 13980 No. of Facilities: 87227 (estimated) No. of Industries: 318 No. of Occupations: 208 No. of Employees: 1447456 (estimated) No. of Female Employees: 245372 (estimated)

 甲乙酮安全信息

[ 符号 ]: GHS02 GHS07
GHS02, GHS07
[ 信号词 ]: Danger
[ 危害声明 ]: H225-H319-H336
[ 补充危害声明 ]: Repeated exposure may cause skin dryness or cracking.
[ 警示性声明 ]: P210-P305 + P351 + P338-P370 + P378-P403 + P235
[ 个人防护装备 ]: Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ 危害码 (欧洲) ]: F,Xi,T
[ 风险声明 (欧洲) ]: R11:Highly Flammable. R36:Irritating to the eyes. R66:Repeated exposure may cause skin dryness or cracking. R67:Vapors may cause drowsiness and dizziness. R39/23/24/25:Toxic: danger of very serious irreversible effects through inhalation, in contact with s
[ 安全声明 (欧洲) ]: S9-S16-S45-S36/37
[ 危险品运输编码 ]: UN 1193 3/PG 2
[ WGK德国 ]: 1
[ RTECS号 ]: EL6475000
[ 包装等级 ]: II
[ 危险类别 ]: 3
[ 海关编码 ]: 2914120000

 甲乙酮合成线路

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