![N-[(2R)-2-吡咯烷甲基]-三氟甲磺酰胺结构式](https://www.chemsrc.com/caspic/466/1186049-30-8.png)
N-[(2R)-2-吡咯烷甲基]-三氟甲磺酰胺结构式
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常用名 | N-[(2R)-2-吡咯烷甲基]-三氟甲磺酰胺 | 英文名 | (R)-1,1,1-TRIFLUORO-N-(PYRROLIDIN-2-YLMETHYL)METHANESULFONAMIDE |
|---|---|---|---|---|
| CAS号 | 1186049-30-8 | 分子量 | 232.22400 | |
| 密度 | N/A | 沸点 | N/A | |
| 分子式 | C6H11F3N2O2S | 熔点 | 210°C | |
| MSDS | 中文版 美版 | 闪点 | N/A | |
| 符号 |
GHS05 |
信号词 | Danger |
| 中文名 | N-[(2R)-2-吡咯烷甲基]-三氟甲磺酰胺 |
|---|---|
| 英文名 | 1,1,1-trifluoro-N-[[(2R)-pyrrolidin-2-yl]methyl]methanesulfonamide |
| 中文别名 | 1,1,1-三氟-N-[(2R)-2-吡咯烷甲基]-甲磺酰胺 | (R)-1,1,1-三氟-n-(吡咯烷-2-甲基)甲烷磺酰胺 |
| 英文别名 | 更多 |
| 熔点 | 210°C |
|---|---|
| 分子式 | C6H11F3N2O2S |
| 分子量 | 232.22400 |
| 精确质量 | 232.04900 |
| PSA | 66.58000 |
| LogP | 1.97810 |
| 储存条件 | 2-8°C |
| 符号 |
GHS05 |
|---|---|
| 信号词 | Danger |
| 危害声明 | H314 |
| 警示性声明 | P280-P305 + P351 + P338-P310 |
| 个人防护装备 | Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges |
| 危害码 (欧洲) | C |
| 危险品运输编码 | 3263.0 |
| 海关编码 | 2935009090 |
| 海关编码 | 2935009090 |
|---|---|
| 中文概述 | 2935009090 其他磺（酰）胺. 增值税率:17.0% 退税率:9.0% 监管条件:无 最惠国关税:6.5% 普通关税:35.0% |
| 申报要素 | 品名, 成分含量, 用途 |
| Summary | 2935009090 other sulphonamides VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:35.0% |
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A recyclable fluorous (S)-pyrrolidine sulfonamide promoted direct, highly enantioselective Michael addition of ketones and aldehydes to nitroolefins in water.
Org. Lett. 8 , 3077-3079, (2006) [reaction: see text] A recycle and reusable fluorous (S)-pyrrolidine sulfonamide organocatalyst has been developed for promoting highly enantio- and diastereoselective Michael addition reactions of ke... |
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Highly enantioselective aldol reactions catalyzed by a recyclable fluorous (S) pyrrolidine sulfonamide on water.
Org. Lett. 10 , 1211-1214, (2008) Fluorous (S) pyrrolidine sulfonamide serves as an efficient promoter for highly enantioselective aldol reactions of ketones and aldehydes with aromatic aldehydes on water. A notable feature of the org... |
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Direct, highly enantioselective pyrrolidine sulfonamide catalyzed Michael addition of aldehydes to nitrostyrenes.
Angew. Chem. Int. Ed. Engl. 44 , 1369-1371, (2005)
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| N-[(2R)-2-PYRROLIDINYLMETHYL]-TRIFLUOROMETHANESULFONAMIDE |
| 1,1,1-Trifluoro-N-[(2R)-2-pyrrolidinylmethyl]-methanesulfonamide |
| (R)-1,1,1-Trifluoro-N-(pyrrolidin-2-ylmethyl)methanesulfonamide |
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