10099-67-9

10099-67-9结构式

常用中文名：硝酸镥六水合物
常用英文名：Nitric acid,lutetium(3+) salt (3:1)
CAS号：10099-67-9
分子式：H₈LuN₃O₁₃
分子量：433.04300
相关类别：无机化工无机盐金属硝酸盐及亚硝酸盐
发布时间：2018-03-06 08:00:00
更新时间：2024-01-12 11:03:27

中文名	硝酸镥六水
英文名	lutetium nitrate hexahydrate
中文别名	无水硝酸镥
英文别名	Lutecium nitrate Trinitric acid lutetium salt LUTETIUM NITRATE TETRAHYDRATE Nitric acid lutetium lutetium trinitrate EINECS 233-241-7 Lutetium nitrate hydrate/

沸点	83ºC at 760 mmHg
分子式	H₈LuN₃O₁₃
分子量	433.04300
精确质量	432.94600
PSA	243.56000
LogP	0.59510
外观性状	crystal \| white
蒸汽压	49.8mmHg at 25°C
储存条件	密闭于阴凉干燥环境中
稳定性	遵照规定使用和储存则不会分解。
水溶解性	soluble H2O, EtOH [CRC10]
分子结构	1、摩尔折射率：无可用 2、摩尔体积（cm³/mol）：无可用 3、等张比容（90.2K）：无可用 4、表面张力（dyne/cm）：无可用 5、极化率：无可用
计算化学	1、疏水参数计算参考值（XlogP）：无可用 2、氢键供体数量：0 3、氢键受体数量：9 4、可旋转化学键数量：0 5、拓扑分子极性表面积（TPSA）：199 6、重原子数量：13 7、表面电荷：0 8、复杂度：18.8 9、同位素原子数量：0 10、确定原子立构中心数量：0 11、不确定原子立构中心数量：0 12、确定化学键立构中心数量：0 13、不确定化学键立构中心数量：0 14、共价键单元数量：4
更多	1. 性状：无可用 2. 密度（g/mL,25/4℃）：无可用 3. 相对蒸汽密度（g/mL,空气=1）：无可用 4. 熔点（ºC）：无可用 5. 沸点（ºC,常压）：无可用 6. 沸点（ºC,5.2kPa）：无可用 7. 折射率：无可用 8. 闪点（ºC）：无可用 9. 比旋光度（º）：无可用 10. 自燃点或引燃温度（ºC）：无可用 11. 蒸气压（kPa,25ºC）：无可用 12. 饱和蒸气压（kPa,60ºC）：无可用 13. 燃烧热（KJ/mol）：无可用 14. 临界温度（ºC）：无可用 15. 临界压力（KPa）：无可用 16. 油水（辛醇/水）分配系数的对数值：无可用 17. 爆炸上限（%,V/V）：无可用 18. 爆炸下限（%,V/V）：无可用 19. 溶解性：无可用

Section 1: Product Identification
Chemical Name:Lutetium (III) nitrate hydrate(99.9%-Lu) (REO)
CAS Registry Number:10099-67-9
Formula:Lu(NO3)3.XH2O
EINECS Number:none
Chemical Family:metal nitrate salts

Synonym:Nitric acid, lutetium(3+) salt

Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title Compound10099-67-9100%no datano data

Section 3: Hazards Identification
Emergency Overview:Irritating to eyes, skin and respiratory tract. May be harmful if swallowed.
Primary Routes of Exposure:Ingestion
Eye Contact:Causes slight to mild irritation of the eyes
Skin Contact:Causes slight to mild irritation of the skin.
Inhalation:Irritating to the nose, mucous membranes and respiratory tract.
Ingestion:Ingestion may lead to dizziness, abdominal cramps, vomiting, bloody diarrhea, weakness, and convulsions.
Acute Health Affects:Irritating to skin, eyes and respiratory tract.
Chronic Health Affects:No information available on long-term chronic effects.
NTP:No
IARC:No
OSHA:No

SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
Flash Point:not applicable
Autoignition Temperature:none
Explosion Limits:none
Extinguishing Medium:carbon dioxide, foam or dry powder
If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
Special Fire Fighting Procedures:
self-contained breathing apparatus and full protective clothing.
Hazardous Combustion andIf involved in a fire this material may emit irritating fumes.
Decomposion Products:
Unusual Fire or Explosion Hazards: Metal nitrates can be oxidizers. Contact with strong reducing agents could lead to fires and/or explosions.

SECTION 6: Accidental Release Measures
Spill and Leak Procedures:Small spills can be mixed with vermiculite or sodium carbonate and swept up.

SECTION 7: Handling and Storage
Handling and Storage:Store in a tightly sealed container. Keep away from heat and direct sunlight.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear protective clothing and gloves.
Ventilation:If possible, handle the material in an efficient fume hood.
If ventilation is not available a respirator should be worn. The use of respirators requires a Respiratory
Respirator:
Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:If possible, handle the material in an efficient fume hood.
Additional Protection:No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:white xtl.
Molecular Weight:360.98
Melting Point:no data
Boiling Point:no data
Vapor Pressure:not applicable
Specific Gravity:no data
Odor:none
Solubility in Water:very soluble

SECTION 10: Stability and Reactivity
Stability:air and moisture stable
Hazardous Polymerization:no hazardous polymerization
Contact with strong reducing agents or organic matter. Some nitrates can explode if heated to high
Conditions to Avoid:
temperatures.
Incompatibility:reducing agents, organic matter, phosphorus and sulfur
Decomposition Products:nitrogen oxides and lutetium salts

SECTION 11: Toxicological Information
RTECS Data:Intraperitoneal (rat); LD50: 258 mg/kg. Intraperitoneal (mouse); LD50: 223 mg/kg.
Carcinogenic Effects:No data available
Mutagenic Effects:No data available
Tetratogenic Effects:No data available

SECTION 12: Ecological Information
Ecological Information:No data available

SECTION 13: Disposal Considerations
Disposal:Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
Shipping Name (CFR):Nitrates, Inorganic, N.O.S.
Hazard Class (CFR):5.1
Additional Hazard Class (CFR):NA
Packaging Group (CFR):II
UN ID Number (CFR):UN# 1477
Shipping Name (IATA):Nitrates, Inorganic, N.O.S.
Hazard Class (IATA):5.1
Additional Hazard Class (IATA):NA
Packaging Group (IATA):II
UN ID Number (IATA):UN# 1477

SECTION 15: Regulatory Information
TSCA:Listed in the TSCA inventory.
SARA (Title 313):Title Compound: See Category Code N511 for reporting.
Second Ingredient:none

SECTION 16 - ADDITIONAL INFORMATION
N/A

毒理学数据:

试验方法：腹腔
摄入剂量： 258毫克/千克
测试对象：啮齿动物-鼠
毒性类型：急性
毒性作用： 1.Details的毒副作用没有报告以外的其他致死剂量值
试验2
试验方法：腹腔
摄入剂量： 223毫克/千克
测试对象：啮齿动物-鼠
毒性类型：急性
毒性作用： 1.Details的毒副作用没有报告以外的其他致死剂量值

生态学数据:

该物质对环境可能有危害，对水体应给予特别注意。

CHEMICAL IDENTIFICATION

RTECS NUMBER :: OK8925000

CAS REGISTRY NUMBER :: 10099-67-9

LAST UPDATED :: 199701

DATA ITEMS CITED :: 4

MOLECULAR FORMULA :: N3-O9.Lu

MOLECULAR WEIGHT :: 361.00

WISWESSER LINE NOTATION :: LU N-O3*3

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 258 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: EQSSDX Environmental Quality and Safety, Supplement. (Stuttgart, Fed. Rep. Ger.) V.1-5, 1975-76. Discontinued. Volume(issue)/page/year: 1,1,1975

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 223 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: EQSSDX Environmental Quality and Safety, Supplement. (Stuttgart, Fed. Rep. Ger.) V.1-5, 1975-76. Discontinued. Volume(issue)/page/year: 1,1,1975 *** REVIEWS *** TOXICOLOGY REVIEW JPMSAE Journal of Pharmaceutical Sciences. (American Pharmaceutical Assoc., 2215 Constitution Ave., NW, Washington, DC 20037) V.50- 1961- Volume(issue)/page/year: 54,663,1965

危害码 (欧洲)	O
风险声明 (欧洲)	R8
安全声明 (欧洲)	17-36/37/39
危险品运输编码	UN 1477
包装等级	II
危险类别	5.1

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