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| 中文名 | N,N'-二苯基-N,N'-二(3-甲基苯基)-1,1'-联苯-4,4'-二胺 |
|---|---|
| 英文名 | N,N'-Bis(3-methylphenyl)-N,N'-diphenylbenzidine |
| 中文别名 |
N,N'-双(3-甲基苯基)-N,N'-二苯联苯胺
n,n'-双(3-甲苯基)-n,n'-二苯基联苯胺 N,N'-二苯基-N,N'-(3-甲基苯基)-1,1'-联苯-4,4'-二胺(TPD) 4,4'-双[N-苯基-N-(间甲苯基)氨基]联苯 N,N'-双(3-甲基苯基)-N,N'-二苯基-[1,1'-联苯]-4,4'-二胺 N,N'-二苯基-N,N'-二(间甲苯基)联苯胺 N,N'-二苯基-N,N'-(3-甲基苯基)-1,1'-联苯-4,4'-二胺 N,N’-二苯基-N,N’-二(3-甲基苯基)-1,1’-联苯-4,4’-二胺 N,N'-双(3-甲基苯基)-N,N'-二苯基-1,1'-联苯-4,4'-二胺 |
| 英文别名 |
N,N′-bis(3-methylphenyl)-N,N′-diphenylbenzidine
N,N'-Bis(3-methylphenyl)-N,N'-bis(phenyl)benzidine 1R CNR&R DR DNR&R C1 N,N'-Bis(3-methylphenyl)-N,N'-diphenyl-4,4'-biphenyldiamine [1,1'-Biphenyl]-4,4'-diamine, N,N-bis(3-methylphenyl)-N,N-diphenyl- N, N'-Bis(3-methylphenyl)-N,N'-bis(phenyl)-benzidine N,N'-Diphenyl-N,N'-di(3-tolyl)benzidine N,N -Diphenyl-N,N-di(m-tolyl)benzidine N,N'-Bis(3-methylphenyl)-N,N'-diphenylbiphenyl-4,4'-diamine MFCD00144965 N4,N4'-Bis(3-methylphenyl)-N4,N4'-diphenyl[1,1'-biphenyl]-4,4'-diamine N,N'-Bis(3-methylphenyl)-N,N'-diphenyl-(1,1'-biphenyl)-4,4'-diamine N,N'-di(3-methylphenyl)-N,N'-di(phenyl)benzidine [1,1'-Biphenyl]-4,4'-diamine, N,N'-bis(3-methylphenyl)-N,N'-diphenyl- EINECS 413-810-8 N,N′-diphenyl-N,N′-di(meta-tolyl)-1,1′-biphenyl-4,4′-diamine [1,1'-Biphenyl]-4,4'-diamine, N4,N4-bis(3-methylphenyl)-N4,N4-diphenyl- |
| 密度 | 1.1±0.1 g/cm3 |
|---|---|
| 沸点 | 680.1±55.0 °C at 760 mmHg |
| 熔点 | 169°C |
| 分子式 | C38H32N2 |
| 分子量 | 516.674 |
| 闪点 | 303.1±19.3 °C |
| 精确质量 | 516.256531 |
| PSA | 6.48000 |
| LogP | 11.94 |
| 外观性状 | 固体 |
| 蒸汽压 | 0.0±2.1 mmHg at 25°C |
| 折射率 | 1.671 |
| 储存条件 | 存放在密封容器内，并放在阴凉，干燥处。储存的地方必须远离氧化剂。 |
| 稳定性 | 远离氧化物。 |
| 水溶解性 | 水溶性：不溶 |
| 分子结构 | 1、 摩尔折射率：168.18 2、 摩尔体积（m3/mol）：449.5 3、 等张比容（90.2K）：1197.7 4、 表面张力（dyne/cm）：50.3 5、 极化率（10-24cm3）：66.67 |
| 计算化学 | 1.疏水参数计算参考值（XlogP）:10.8 2.氢键供体数量:0 3.氢键受体数量:2 4.可旋转化学键数量:7 5.互变异构体数量:无 6.拓扑分子极性表面积6.5 7.重原子数量:40 8.表面电荷:0 9.复杂度:660 10.同位素原子数量:0 11.确定原子立构中心数量:0 12.不确定原子立构中心数量:0 13.确定化学键立构中心数量:0 14.不确定化学键立构中心数量:0 15.共价键单元数量:1 |
| 更多 | 1. 性状：固体。 2. 密度（g/mL,25/4℃）：未确定 3. 相对蒸汽密度（g/mL,空气=1）：未确定 4. 熔点（ºC）：175-177 5. 沸点（ºC,常压）：未确定 6. 沸点（ºC,5.2kPa）：未确定 7. 折射率：未确定 8. 闪点（ºC）：未确定 9. 比旋光度（º）：未确定 10. 自燃点或引燃温度（ºC）：未确定 11. 蒸气压（kPa,25ºC）：未确定 12. 饱和蒸气压（kPa,60ºC）：未确定 13. 燃烧热（KJ/mol）：未确定 14. 临界温度（ºC）：未确定 15. 临界压力（KPa）：未确定 16. 油水（辛醇/水）分配系数的对数值：未确定 17. 爆炸上限（%,V/V）：未确定 18. 爆炸下限（%,V/V）： 19. 溶解性：未确定。 |
Synonym:N,N'-Diphenyl-N,N'-bis(3-methylphenyl)-(1,1'-diphenyl)-4,4'-diamine Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 51/53 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.The toxicological properties of this material have not been fully investigated. Potential Health Effects Eye: May cause eye irritation. Skin: May cause skin irritation. Ingestion: May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated. Inhalation: May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. Chronic: No information found. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Ingestion: Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Runoff from fire control or dilution water may cause pollution. Extinguishing Media: Use agent most appropriate to extinguish fire. Use dry chemical, carbon dioxide, or halon extinguisher. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions. Provide ventilation. Section 7 - HANDLING and STORAGE Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Storage: Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels. Exposure Limits CAS# 65181-78-4: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Crystals Color: yellowish-white Odor: odorless pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: 168 deg C Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Insoluble. Specific Gravity/Density: Molecular Formula: C38H32N2 Molecular Weight: 516.2374 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Incompatible materials, dust generation, strong oxidants. Incompatibilities with Other Materials: Oxidizing agents. Hazardous Decomposition Products: Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, various hydrocarbons. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 65181-78-4 unlisted. LD50/LC50: Not available. Carcinogenicity: N,N'-Diphenyl-N,N'-di-m-tolylbenzidine - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Products which are considered hazardous for supply are classified as Special Waste and the disposal of such chemicals is covered by regulations which may vary according to location. Contact a specialist disposal company or the local waste regulator for advice. Empty containers must be decontaminated before returning for recycling. Section 14 - TRANSPORT INFORMATION IATA Not regulated as a hazardous material. IMO Not regulated as a hazardous material. RID/ADR Not regulated as a hazardous material. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: N Risk Phrases: R 51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Safety Phrases: S 61 Avoid release to the environment. Refer to special instructions/safety data sheets. WGK (Water Danger/Protection) CAS# 65181-78-4: No information available. Canada CAS# 65181-78-4 is listed on Canada's NDSL List. CAS# 65181-78-4 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 65181-78-4 is listed on the TSCA inventory. SECTION 16 - ADDITIONAL INFORMATION N/A |
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生态学数据: 通常对水是不危害的，若无政府许可，勿将材料排入周围环境。
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| 符号 |
GHS09 |
|---|---|
| 危害声明 | H411 |
| 警示性声明 | P273 |
| 个人防护装备 | Eyeshields;Gloves |
| 危害码 (欧洲) | N |
| 风险声明 (欧洲) | R36/37/38 |
| 安全声明 (欧洲) | S26-S36/37/39-S61 |
| 危险品运输编码 | 3077 |
| 海关编码 | 2921590090 |
| 上游产品 9 | |
|---|---|
| 下游产品 0 | |
| 海关编码 | 2921590090 |
|---|---|
| 中文概述 | 2921590090. 其他芳香多胺及衍生物及它们的盐. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:30.0% |
| 申报要素 | 品名, 成分含量, 用途 |
| Summary | 2921590090. other aromatic polyamines and their derivatives; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0% |
