31895-22-4

• 常用中文名：杀虫环标准溶液
• 常用英文名：Thiocyclam hydrogen oxalate
• CAS号：31895-22-4
• 分子式：C₇H₁₃NO₄S₃
• 分子量：271.37700
• 相关类别： 化学农药原药 杀虫剂 沙蚕毒类杀虫剂
• 发布时间：2018-06-15 16:39:54
• 更新时间：2026-07-01 17:20:58
• 【用途一】
  选择性杀虫剂。具有胃毒、触杀、内吸作用。防治鳞片目和鞘翅目害虫的持效期为7-14d，也可防治寄生线虫，如水稻白尖线虫，对一些作物的锈病和白穗病也有一定的防效。

名称

• 中文名: 杀虫环草酸盐
• 英文名: thiocyclam oxalate
• 中文别名: 杀虫环草酸（标准品）; 易卫杀; 草酸氢杀虫环; N,N-二甲基-1,2,3-三硫杂环己烷-5-胺草酸盐; 虫噻烷; N,N-二甲基1,2,3-三硫杂环已烷-5-胺基草酸盐; N,N-二甲基-1,2,3-三硫杂环已烷-5-胺草酸盐; N,N-二甲基-1,2,3-三硫杂环已烷-5-胺草酸盐,硫环杀,易卫杀; 甲醇中杀虫环溶液标准物质; 杀虫环草酸盐检测标准品; 硫环杀; 杀虫环氢草酸标准品; 甲硫环; 杀虫环标准溶液(10ΜG/ML,U=,基体:甲醇); 易卫杀草酸盐(杀虫环草酸盐); 甲醇中杀虫环草酸盐(以杀虫环计); 甲醇中草酸氢杀虫环溶液,100ΜG/ML; 草酸氢硫环胺; N,N-二甲基-1,2,3-三硫杂环己-5-基胺; 甲醇中杀虫环草酸盐; N,N-二甲基-1,2,3-三硫杂环己-5-胺及其草酸盐; 杀虫环 草酸氢盐; 杀虫环草酸; 杀螟环; 甲醇中杀虫环草酸盐标准品; 杀虫环草酸(标准品); 杀虫环/硫环杀/易卫杀; 杀虫环; 甲醇中杀虫环草酸盐溶液标准物质; 杀虫环草酸氢盐分析标准品; 易卫杀草酸盐(杀虫环草酸盐) 标准品; 二甲基亚砜中杀虫环草酸盐; 3-三硫杂环已烷-5-胺草酸盐
• 英文别名: N,N-dimethyl-1,2,3-trithiaxan-5-ylamine oxalate; thiocyclam(ethanedioate1:1); n,n-dimethyl-1,2,3-trithian-5-aminehydrogenoxalate; MFCD00211369; oxalic acid—N,N-dimethyl-1,2,3-trithian-5-amine; bis(1,2,3-trithiacyclohexyldimethylammonium) oxalate thiocyclam-oxalate; THIOCYCLAM HYDROGEN OXALATE STANDD; Sulfoxane; ThiocyclaM-hydrogen oxalate solution; san155i; n,n-dimethyl-1,2,3-trithian-5-ylammoniumhydrogenoxalate; Thiocyclam hydrogenoxalate in DMSO; Bis(1,2,3-trithiacyclohexyldimethylammon; Thiocyclam hydrogenoxalate Solution in Methanol,100μg/mL; Oxalic acid compound with cyclohexylsulfamothioic O-acid (1:1); thiocyclamhydrogeneoxalate; C17480000 Thiocyclam hydrogenoxalate; Thiocyclam Hydrogen oxalate @100 μg/mL in Methanol; Thiocyclam oxalate; EINECS 250-859-2; Evisect; N,N-dimethyl-1,2,3-trithian-5-amine ethanedioate (1:1); 2,3-trithian-5-amine,n,n-dimethyl-ethanedioate(1:1); 5-(dimethylamino)-v-trithianoxalate; Thiocyclam hydrogenoxalate in Methanol; 5-dimethylamino-1,2,3-trithianehydrogenoxalate; n,n-dimethyl-1,2,3-trithian-5-amine,ethanedioate(1:1); 5-Di-methylamino-1,2,3-trithiane; hiocyclamoxalate; Chlorpyrifos Impurity 17 (Dicapthon); bis(1,2,3-trithiacyclohexyldimethylammonium)oxalate; NERISECT; N,N-dimethyl-1,2,3-trithian-5-ylamine oxalate (1:1); THIOCYCLAM HYDROGEN OXALATE; N,N-Dimetnyl-1,2,3-trithian-5-ylamine; san1551; san155; Thiocyclam hydrogenoxalate 10 μg/ml Methanol; Thiocyclam Hydrogen Oxalate@1000 μg/mL in Methanol; Thiocyclam hydrogenoxalate; evisekt; FICOLL(R); ThiocyclaM-hydrogen oxala

物化性质

• 沸点: 280.7ºC at 760mmHg
• 熔点: 125-128ºC
• 分子式: C₇H₁₃NO₄S₃
• 分子量: 271.37700
• 闪点: 130 °C
• 精确质量: 271.00100
• PSA: 153.74000
• LogP: 1.11540
• 外观性状: 无色结晶
• 储存条件:

  密封、在 0-6 ºC下保存

• 稳定性:

  如果遵照规格使用和储存则不会分解，未有已知危险反应

• 计算化学:

  1.疏水参数计算参考值（XlogP）:无

  2.氢键供体数量:2

  3.氢键受体数量:8

  4.可旋转化学键数量:2

  5.互变异构体数量:无

  6.拓扑分子极性表面积154

  7.重原子数量:15

  8.表面电荷:0

  9.复杂度:152

  10.同位素原子数量:0

  11.确定原子立构中心数量:0

  12.不确定原子立构中心数量:0

  13.确定化学键立构中心数量:0

  14.不确定化学键立构中心数量:0

  15.共价键单元数量:2

• 更多:

  1. 性状：无臭无色结晶

  2. 密度（g/mL,20℃）：未确定

  3. 相对蒸汽密度（g/mL,空气=1）：未确定

  4. 熔点（ºC）：125-128

  5. 沸点（ºC,常压）：未确定

  6. 沸点（ºC,KPa）：未确定

  7. 折射率：未确定

  8. 闪点（ºC）：130

  9. 比旋光度（º）：未确定

  10. 自燃点或引燃温度（ºC）：未确定

  11. 蒸气压（Pa,20ºC）：5.3×10-2

  12. 饱和蒸气压（KPa,20ºC）：未确定

  13. 燃烧热（KJ/mol）：未确定

  14. 临界温度（ºC）：未确定

  15. 临界压力（KPa）：未确定

  16. 油水（辛醇/水）分配系数的对数值：未确定

  17. 爆炸上限（%,V/V）：未确定

  18. 爆炸下限（%,V/V）：未确定

  19. 溶解性：23℃水中溶解度为84g/L，丙酮500mg/L，乙醇1.9g/L，甲醇17g/L，二甲苯＜10g/L，不溶于煤油。

毒性和生态

生态学数据: 若无政府许可，勿将材料排入周围环境。 CHEMICAL IDENTIFICATION RTECS NUMBER : YL8300000 CHEMICAL NAME : v-Trithiane, 5-(dimethylamino)-, oxalate CAS REGISTRY NUMBER : 31895-22-4 LAST UPDATED : 199604 DATA ITEMS CITED : 14 MOLECULAR FORMULA : C5-H11-N-S3.C2-H2-O4 MOLECULAR WEIGHT : 271.39 WISWESSER LINE NOTATION : T6SSSTJ DN1&1 &QVVQ HEALTH HAZARD DATA ACUTE TOXICITY DATA TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 195 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : KSKZAN Khimiya v Sel'skom Khozyaistve. Chemistry in Agriculture. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) No.1- 1963- Volume(issue)/page/year: 16(2),59,1978 TYPE OF TEST : LC50 - Lethal concentration, 50 percent kill ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Rodent - rat DOSE/DURATION : >4500 mg/m3 TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : 85JFAN "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd, eds., Nottingham, Royal Soc. of Chemistry, 1983-86 Volume(issue)/page/year: A393,1983 TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Administration onto the skin SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 1 gm/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : FMCHA2 Farm Chemicals Handbook. (Meister Pub., 37841 Euclid Ave., Willoughy, OH 44094) Volume(issue)/page/year: -,C301,1991 TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 22900 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : NNGADV Nippon Noyaku Gakkaishi. Journal of the Pesticide Science Society of Japan. (Nippon Noyaku Gakkai, 1-43-11, Komagome, Toshima-ku, Tokyo 170, Japan) V.1- 1976- Volume(issue)/page/year: 12,339,1987 TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Subcutaneous SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 27900 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : NNGADV Nippon Noyaku Gakkaishi. Journal of the Pesticide Science Society of Japan. (Nippon Noyaku Gakkai, 1-43-11, Komagome, Toshima-ku, Tokyo 170, Japan) V.1- 1976- Volume(issue)/page/year: 12,339,1987 TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 156 mg/kg TOXIC EFFECTS : Behavioral - tremor Behavioral - convulsions or effect on seizure threshold Behavioral - ataxia REFERENCE : GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 50(11),71,1985 TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 37200 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : NNGADV Nippon Noyaku Gakkaishi. Journal of the Pesticide Science Society of Japan. (Nippon Noyaku Gakkai, 1-43-11, Komagome, Toshima-ku, Tokyo 170, Japan) V.1- 1976- Volume(issue)/page/year: 12,339,1987 TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Subcutaneous SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 33900 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : NNGADV Nippon Noyaku Gakkaishi. Journal of the Pesticide Science Society of Japan. (Nippon Noyaku Gakkai, 1-43-11, Komagome, Toshima-ku, Tokyo 170, Japan) V.1- 1976- Volume(issue)/page/year: 12,339,1987 TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Bird - quail DOSE/DURATION : 3450 ug/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,816,1991 ** OTHER MULTIPLE DOSE TOXICITY DATA ** TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 2184 mg/kg/13W-C TOXIC EFFECTS : Endocrine - changes in spleen weight Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - transaminases Related to Chronic Data - death REFERENCE : NNGADV Nippon Noyaku Gakkaishi. Journal of the Pesticide Science Society of Japan. (Nippon Noyaku Gakkai, 1-43-11, Komagome, Toshima-ku, Tokyo 170, Japan) V.1- 1976- Volume(issue)/page/year: 12,339,1987 TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 328 mg/kg/1Y-I TOXIC EFFECTS : Behavioral - alteration of classical conditioning Nutritional and Gross Metabolic - weight loss or decreased weight gain Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - transaminases REFERENCE : GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 50(11),71,1985 TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 4380 mg/kg/2Y-C TOXIC EFFECTS : Behavioral - food intake (animal) Blood - changes in leukocyte (WBC) count Nutritional and Gross Metabolic - weight loss or decreased weight gain REFERENCE : NNGADV Nippon Noyaku Gakkaishi. Journal of the Pesticide Science Society of Japan. (Nippon Noyaku Gakkai, 1-43-11, Komagome, Toshima-ku, Tokyo 170, Japan) V.1- 1976- Volume(issue)/page/year: 12,339,1987 TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Mammal - dog DOSE/DURATION : 1313 mg/kg/20W-C TOXIC EFFECTS : Behavioral - convulsions or effect on seizure threshold Behavioral - food intake (animal) Endocrine - other changes REFERENCE : NNGADV Nippon Noyaku Gakkaishi. Journal of the Pesticide Science Society of Japan. (Nippon Noyaku Gakkai, 1-43-11, Komagome, Toshima-ku, Tokyo 170, Japan) V.1- 1976- Volume(issue)/page/year: 12,339,1987 TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Mammal - dog DOSE/DURATION : 6844 mg/kg/2Y-C TOXIC EFFECTS : Behavioral - ataxia Nutritional and Gross Metabolic - weight loss or decreased weight gain Related to Chronic Data - death REFERENCE : NNGADV Nippon Noyaku Gakkaishi. Journal of the Pesticide Science Society of Japan. (Nippon Noyaku Gakkai, 1-43-11, Komagome, Toshima-ku, Tokyo 170, Japan) V.1- 1976- Volume(issue)/page/year: 12,339,1987

安全

• 符号: GHS07, GHS09
• 信号词: Warning
• 危害声明: H302 + H312-H410
• 警示性声明: P273-P280-P501
• 个人防护装备: dust mask type N95 (US);Eyeshields;Faceshields;Gloves
• 危害码 (欧洲): Xn: Harmful;N: Dangerous for the environment;
• 风险声明 (欧洲): R21/22
• 安全声明 (欧洲): S36/37-S46-S60-S61
• 危险品运输编码: 2588
• RTECS号: YL8300000
• 包装等级: III
• 危险类别: 6.1(b)
• 海关编码: 2934999090

制备

1、 由氯丙烯为起始原料，经胺化、氯化制得3-N,N-二甲氨基-1,2-二氨丙烷二氯丙烷，其盐酸盐和硫代硫酸钠反应制得2-N，N-二甲氨基-1-硫代硫酸基-3-硫代硫酸钠基丙烷（简称单钠盐），再与硫化钠环化、成盐而得。

海关

海关编码	2934999090
中文概述	2934999090. 其他杂环化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%
申报要素	品名, 成分含量, 用途
Summary	2934999090. other heterocyclic compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%