14364-93-3

• 常用中文名：三甲基碘化铂
• 常用英文名：Iodo(trimethyl)platinum
• CAS号：14364-93-3
• 分子式：C₃H₉IPt
• 分子量：367.092
• 发布时间：2018-04-18 08:00:00
• 更新时间：2024-01-09 17:25:35

名称

• 中文名: 三甲基碘化铂
• 英文名: Iodotrimethylplatinum(IV)
• 英文别名: carbanide,iodoplatinum; Platinum, iodotrimethyl-; Trimethylplatinum(IV) iodide; MFCD00013702; Iodo(trimethyl)platinum

物化性质

• 熔点: 250ºC (dec.)
• 分子式: C₃H₉IPt
• 分子量: 367.092
• 精确质量: 366.939697
• 外观性状: 固体
• 储存条件:

  常温密闭避光，通风干燥

• 稳定性:

  常温常压下稳定

  避免的物料： 卤素

• 分子结构:

  1、摩尔折射率：无可用的

  2、摩尔体积（cm³/mol）：无可用的

  3、等张比容（90.2K）：无可用的

  4、表面张力（dyne/cm）：无可用的

  5、介电常数：无可用的

  6、极化率（10^-24cm³）：无可用的

  7、单一同位素质量：366.939685 Da

  8、标称质量：367 Da

  9、平均质量：367.092 Da

• 计算化学:

  1.疏水参数计算参考值（XlogP）:无

  2.氢键供体数量:0

  3.氢键受体数量:3

  4.可旋转化学键数量:0

  5.互变异构体数量:无

  6.拓扑分子极性表面积0

  7.重原子数量:5

  8.表面电荷:-3

  9.复杂度:6.9

  10.同位素原子数量:0

  11.确定原子立构中心数量:0

  12.不确定原子立构中心数量:0

  13.确定化学键立构中心数量:0

  14.不确定化学键立构中心数量:0

  15.共价键单元数量:4

• 更多:

  1. 性状：浅橙色晶体

  2. 密度（g/mL,25/4℃）：未确定

  3. 相对蒸汽密度（g/mL,空气=1）：未确定

  4. 熔点（ºC）：未确定

  5. 沸点（ºC,常压）：未确定

  6. 沸点（ºC,5.2kPa）：未确定

  7. 折射率：未确定

  8. 闪点（ºC）：未确定

  9. 比旋光度（º）：未确定

  10. 自燃点或引燃温度（ºC）：未确定

  11. 蒸气压（kPa,25ºC）：未确定

  12. 饱和蒸气压（kPa,60ºC）：未确定

  13. 燃烧热（KJ/mol）：未确定

  14. 临界温度（ºC）：未确定

  15. 临界压力（KPa）：未确定

  16. 油水（辛醇/水）分配系数的对数值：未确定

  17. 爆炸上限（%,V/V）：未确定

  18. 爆炸下限（%,V/V）：未确定

  19. 溶解性：不能溶解的

MSDS

Section 1: Product Identification Chemical Name:Iodotrimethylplatinum (IV), 99% CAS Registry Number:14364-93-3 Formula:(CH3)3PtI EINECS Number:None Chemical Family:organometallic complexes Synonym:Trimethylplatinum iodide Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title Compound14364-93-3100%1mg/m3(as-Pt)no data Section 3: Hazards Identification Irritating to skin, eyes and respiratory tract. Exposure to platinum compounds has been shown to cause Emergency Overview: wheezing, coughing, and running of the nose. Skin contact can lead to dermatitis. Primary Routes of Exposure:Ingestion, inhalation, skin Eye Contact:Causes mild to moderate irritation of the eyes. Skin Contact:Causes slight to mild irritation of the skin. Irritating to the nose, mucous membranes and respiratory tract. Inhalation of the dust may cause wheezing, Inhalation: coughing, shortness of breath. Ingestion:Ingestion may lead to dizziness, abdominal cramps, vomiting, bloody diarrhea, weakness, and convulsions. Irritating to skin, eyes and respiratory tract. Exposure to platinum compounds may lead to wheezing, coughing, Acute Health Affects: and running of the nose. Skin exposure may lead to dermatitis. Chronic Health Affects:No information available on long-term chronic effects. NTP:No IARC:No OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if Skin Exposure: irritation persists. Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty Inhalation: in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce Ingestion: vomiting only if directed by medical personnel. SECTION 5: Fire Fighting Measures Flash Point:not applicable Autoignition Temperature:none Explosion Limits:none Extinguishing Medium:carbon dioxide, foam or dry powder If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure Special Fire Fighting Procedures: self- contained breathing apparatus and full protective clothing. Hazardous Combustion andIf involved in a fire this material may emit toxic and corrosive fumes. Decomposion Products: Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards. SECTION 6: Accidental Release Measures Small spills can be mixed with vermiculite, sodium carbonate or other suitable non combustible adsorbent and Spill and Leak Procedures: swept up. SECTION 7: Handling and Storage Handling and Storage:Store in a cool, dry place in a tightly sealed container. SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory. Skin Protection:Wear protective clothing and gloves. Ventilation:To minimize exposure, handle the material in an efficient fume hood. If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Respirator: Protection Program to be in compliance with 29 CFR 1910.134. Ventilation:To minimize exposure, handle the material in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:light orange xtl. Molecular Weight:367.09 Melting Point:no data Boiling Point:no data Vapor Pressure:not applicable Specific Gravity:no data Odor:none Solubility in Water:insoluble SECTION 10: Stability and Reactivity Stability:air and moisture stable Hazardous Polymerization:no hazardous polymerization Conditions to Avoid:none Incompatibility:oxidizing agents, halogens, and active metals Decomposition Products:carbon monoxide, carbon dioxide, iodine, and platinum salts. SECTION 11: Toxicological Information RTECS Data:No information available in the RTECS files. Carcinogenic Effects:No data Mutagenic Effects:No data Tetratogenic Effects:No data SECTION 12: Ecological Information Ecological Information:No information available SECTION 13: Disposal Considerations Disposal:Dispose of according to local, state and federal regulations. SECTION 14: Transportation Shipping Name (CFR):Non-hazardous Hazard Class (CFR):NA Additional Hazard Class (CFR):NA Packaging Group (CFR):NA UN ID Number (CFR):NA Shipping Name (IATA):Non-hazardous Hazard Class (IATA):NA Additional Hazard Class (IATA):NA Packaging Group (IATA):NA UN ID Number (IATA):NA SECTION 15: Regulatory Information TSCA:Listed in the TSCA inventory. SARA (Title 313):Not regulated by Title 313. Second Ingredient:None SECTION 16 - ADDITIONAL INFORMATION N/A

毒性和生态

毒理学数据: 1、急性毒性：主要的刺激性影响： 在皮肤上面：刺激皮肤和粘膜； 在眼睛上面：刺激的影响； 2、致敏作用：白金盐，尤其是离子态的白金卤化物可引起严重的过敏反应。 生态学数据: 通常对水是不危害的，若无政府许可，勿将材料排入周围环境。

安全

• 危害码 (欧洲): Xn
• 风险声明 (欧洲): 36/37/38
• 安全声明 (欧洲): 26-36/37/39

合成路线

13454-96-1 ~% 14364-93-3 22295-11-0

文献：Journal of the American Chemical Society, , vol. 60, p. 3085

917-64-6 ~% 14364-93-3

文献：Journal of the American Chemical Society, , vol. 75, p. 2064

13454-96-1 ~% 14364-93-3

文献：Journal of the Chemical Society, , vol. 95, p. 572 Proceedings of the Chemical Society, London, , vol. 23, p. 87

917-64-6 12012-50-9 ~% 14364-93-3

文献：Chatt, J. in: Plesch, P. H., Cationic polymerisation and related complexes, Cambridge 1953, S. 50

917-64-6 16405-35-9 ~% 14364-93-3

文献：Doklady, , vol. 57, p. 259 - 261

上下游产品

上游产品  4
13454-96-1 917-64-6 12012-50-9 16405-35-9
下游产品  1
94442-22-5