145214-05-7

145214-05-7结构式

常用中文名：2-(三正丁基锡基)恶唑
常用英文名：2-(Tributylstannyl)-1,3-oxazole
CAS号：145214-05-7
分子式：C₁₅H₂₉NOSn
分子量：358.107
相关类别：有机原料有机金属盐
发布时间：2018-07-30 19:16:17
更新时间：2024-01-06 00:39:12

化源商城直购

中文名	2-(三正丁基锡基)噁唑
英文名	tributyl(1,3-oxazol-2-yl)stannane
中文别名	2 - (三正丁基锡基)恶唑 2-(三正丁基锡基)恶唑 2-(三-N-丁基甲锡烷基)唑
英文别名	tributylstannyloxazole 2-(Tri-n-butylstannyl)oxazole 2-(Tributylstannyl)-1,3-oxazole 2-tributylstannanyl-oxazole 2-(Tributylstannyl)oxazole Oxazole,2-(tributylstannyl) MFCD06798076 Oxazole, 2-(tributylstannyl)- 2-(tributylstannanyl)-1,3-oxazole oxazole-2-SnBu3

密度	1.71 g/mL at 25ºC(lit.)
沸点	340.6±25.0 °C at 760 mmHg
熔点	227-228℃
分子式	C₁₅H₂₉NOSn
分子量	358.107
闪点	159.8±23.2 °C
精确质量	359.127106
PSA	26.03000
LogP	8.61
蒸汽压	0.0±0.7 mmHg at 25°C
折射率	n20/D 1.4930(lit.)
储存条件	密封储存，储存于阴凉、干燥的库房。防潮，用惰性气体保护。
稳定性	常温常压下稳定，避免与强氧化剂接触。
水溶解性	Insoluble in water.
计算化学	1.疏水参数计算参考值（XlogP）:无 2.氢键供体数量:0 3.氢键受体数量:2 4.可旋转化学键数量:10 5.互变异构体数量:无 6.拓扑分子极性表面积26 7.重原子数量:18 8.表面电荷:0 9.复杂度:189 10.同位素原子数量:0 11.确定原子立构中心数量:0 12.不确定原子立构中心数量:0 13.确定化学键立构中心数量:0 14.不确定化学键立构中心数量:0 15.共价键单元数量:1
更多	1. 性状：无色液体 2. 密度（g/mL,25℃）：1.71 3. 相对蒸汽密度（g/mL,空气=1）：未确定 4. 熔点（ºC）：未确定 5. 沸点（ºC,常压）：未确定 6. 沸点（ºC，0.2mmHg）：108-110 7. 折射率(n20/D)：1.4930 8. 闪点（ºC）：＞110 9. 比旋光度（º）：未确定 10. 自燃点或引燃温度（ºC）：未确定 11. 蒸气压（mmHg,20ºC）：未确定 12. 饱和蒸气压（kPa,25ºC）：未确定 13. 燃烧热（KJ/mol）：未确定 14. 临界温度（ºC）：未确定 15. 临界压力（KPa）：未确定 16. 油水（辛醇/水）分配系数的对数值：未确定 17. 爆炸上限（%,V/V）：未确定 18. 爆炸下限（%,V/V）：未确定 19. 溶解性：未确定

SECTION 1: Identification of the substance/mixture and of the company/undertaking
Product identifiers
Product name: 2-(Tri-n-butylstannyl)oxazole
REACH No.: A registration number is not available for this substance as the substance
or its uses are exempted from registration, the annual tonnage does not
require a registration or the registration is envisaged for a later

registration deadline.
CAS-No.: 145214-05-7
Relevant identified uses of the substance or mixture and uses advised against
Identified uses: Laboratory chemicals, Manufacture of substances

SECTION 2: Hazards identification
Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Acute toxicity, Oral (Category 3), H301
Specific target organ toxicity - repeated exposure (Category 1), H372
Acute toxicity, Dermal (Category 4), H312
Eye irritation (Category 2), H319
Skin irritation (Category 2), H315
Acute aquatic toxicity (Category 1), H400
Chronic aquatic toxicity (Category 1), H410
For the full text of the H-Statements mentioned in this Section, see Section 16.
Classification according to EU Directives 67/548/EEC or 1999/45/EC
T ToxicR25, R48/23/25
Xn HarmfulR21
Xi IrritantR36/38
N Dangerous for theR50/53
environment
For the full text of the R-phrases mentioned in this Section, see Section 16.
Label elements
Labelling according Regulation (EC) No 1272/2008
Pictogram
Signal wordDanger
Hazard statement(s)
H301Toxic if swallowed.
H312Harmful in contact with skin.
H315Causes skin irritation.
H319Causes serious eye irritation.
H372Causes damage to organs through prolonged or repeated exposure.
H410Very toxic to aquatic life with long lasting effects.
Precautionary statement(s)
P273Avoid release to the environment.
P280Wear protective gloves/ protective clothing.
P301 + P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/
physician.
P305 + P351 + P338IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P314Get medical advice/ attention if you feel unwell.
P501Dispose of contents/ container to an approved waste disposal plant.
Supplemental Hazardnone
Statements
Other hazards - none

SECTION 3: Composition/information on ingredients
Substances
Formula: C15H29NOSn
Molecular Weight: 358,11 g/mol
CAS-No.: 145214-05-7
Hazardous ingredients according to Regulation (EC) No 1272/2008
ComponentClassificationConcentration
2-(Tri-n-butylstannyl)oxazole
Acute Tox. 3; Acute Tox. 4;-
Skin Irrit. 2; Eye Irrit. 2; STOT
RE 1; Aquatic Acute 1; Aquatic
Chronic 1; H301, H312, H315,
H319, H372, H410
Hazardous ingredients according to Directive 1999/45/EC
ComponentClassificationConcentration
2-(Tri-n-butylstannyl)oxazole
T, N, R21 - R25 - R36/38 --
R48/23/25 - R50/53
For the full text of the H-Statements and R-Phrases mentioned in this Section, see Section 16

SECTION 4: First aid measures
Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a physician.
In case of eye contact
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in
section 11
Indication of any immediate medical attention and special treatment needed
no data available

SECTION 5: Firefighting measures
Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special hazards arising from the substance or mixture
Carbon oxides, nitrogen oxides (NOx), Tin/tin oxides
Advice for firefighters
Wear self contained breathing apparatus for fire fighting if necessary.
Further information
no data available

SECTION 6: Accidental release measures
Personal precautions, protective equipment and emergency procedures
Wear respiratory protection. Avoid breathing vapours, mist or gas. Ensure adequate ventilation.
Evacuate personnel to safe areas.
For personal protection see section 8.
Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the
environment must be avoided.
Methods and materials for containment and cleaning up
Soak up with inert absorbent material and dispose of as hazardous waste. Keep in suitable, closed
containers for disposal.
Reference to other sections
For disposal see section 13.

SECTION 7: Handling and storage
Precautions for safe handling
Avoid contact with skin and eyes. Avoid inhalation of vapour or mist.
For precautions see section 2.2.
Conditions for safe storage, including any incompatibilities
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are
opened must be carefully resealed and kept upright to prevent leakage.
Moisture sensitive. Store under inert gas.
Specific end use(s)
A part from the uses mentioned in section 1.2 no other specific uses are stipulated

SECTION 8: Exposure controls/personal protection
Control parameters
Components with workplace control parameters
Exposure controls
Appropriate engineering controls
Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling
the product.
Personal protective equipment
Eye/face protection
Face shield and safety glasses Use equipment for eye protection tested and approved under
appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique
(without touching glove's outer surface) to avoid skin contact with this product. Dispose of
contaminated gloves after use in accordance with applicable laws and good laboratory practices.
Wash and dry hands.
The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and
the standard EN 374 derived from it.
Body Protection
Complete suit protecting against chemicals, The type of protective equipment must be selected
according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection
Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator
with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup
to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air
respirator. Use respirators and components tested and approved under appropriate government
standards such as NIOSH (US) or CEN (EU).
Control of environmental exposure
Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into
the environment must be avoided.

SECTION 9: Physical and chemical properties
Information on basic physical and chemical properties
a) AppearanceForm: liquid
Colour: colourless
b) Odourno data available
c) Odour Thresholdno data available
d) pHno data available
e) Melting point/freezingno data available
point
f) Initial boiling point and 108 - 110 °C at 0,3 hPa - lit.
boiling range
g) Flash point> 110 °C - closed cup
h) Evapouration rateno data available
i) Flammability (solid, gas) no data available
j) Upper/lowerno data available
flammability or
explosive limits
k) Vapour pressureno data available
l) Vapour densityno data available
m) Relative density1,71 g/cm3 at 25 °C
n) Water solubilityno data available
o) Partition coefficient: n- no data available
octanol/water
p) Auto-ignitionno data available
temperature
q) Decompositionno data available
temperature
r) Viscosityno data available
s) Explosive propertiesno data available
t) Oxidizing propertiesno data available
Other safety information
no data available

SECTION 10: Stability and reactivity
Reactivity
no data available
Chemical stability
Stable under recommended storage conditions.
Possibility of hazardous reactions
no data available
Conditions to avoid
no data available
Incompatible materials
Strong oxidizing agents
Hazardous decomposition products
Other decomposition products - no data available
In the event of fire: see section 5

SECTION 11: Toxicological information
Information on toxicological effects
Acute toxicity
no data available
Skin corrosion/irritation
no data available
Serious eye damage/eye irritation
no data available
Respiratory or skin sensitisation
no data available
Germ cell mutagenicity
no data available
Carcinogenicity
IARC:No component of this product present at levels greater than or equal to 0.1% is identified as
probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity
no data available
Specific target organ toxicity - single exposure
no data available
Specific target organ toxicity - repeated exposure
Causes damage to organs through prolonged or repeated exposure.
Aspiration hazard
no data available
Additional Information
RTECS: Not available

SECTION 12: Ecological information
Toxicity
no data available
Persistence and degradability
no data available
Bioaccumulative potential
no data available
Mobility in soil
no data available
Results of PBT and vPvB assessment
PBT/vPvB assessment not available as chemical safety assessment not required/not conducted
Other adverse effects
Very toxic to aquatic life with long lasting effects.

SECTION 13: Disposal considerations
Waste treatment methods
Product
Offer surplus and non-recyclable solutions to a licensed disposal company.
Contaminated packaging
Dispose of as unused product.

SECTION 14: Transport information
UN number
ADR/RID: 2788IMDG: 2788IATA: 2788
UN proper shipping name
ADR/RID: ORGANOTIN COMPOUND, LIQUID, N.O.S. (2-(Tri-n-butylstannyl)oxazole)
IMDG: ORGANOTIN COMPOUND, LIQUID, N.O.S. (2-(Tri-n-butylstannyl)oxazole)
IATA:Organotin compound, liquid, n.o.s. (2-(Tri-n-butylstannyl)oxazole)
Transport hazard class(es)
ADR/RID: 6.1IMDG: 6.1IATA: 6.1
Packaging group
ADR/RID: IIIIMDG: IIIIATA: III
Environmental hazards
ADR/RID: yesIMDG Marine pollutant: yesIATA: no
Special precautions for user
no data available

SECTION 15 - REGULATORY INFORMATION
N/A

SECTION 16 - ADDITIONAL INFORMATION
N/A

符号	GHS06, GHS08, GHS09
信号词	Danger
危害声明	H301-H312-H315-H319-H372-H410
警示性声明	Missing Phrase - N15.00950417-P260-P280-P305 + P351 + P338
个人防护装备	Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
危害码 (欧洲)	T: Toxic;N: Dangerous for the environment;
风险声明 (欧洲)	R21
安全声明 (欧洲)	S35
危险品运输编码	UN 2788 6.1/PG 3
WGK德国	3
海关编码	2934999090

288-42-6

1461-22-9

145214-05-7

文献：US5347013 A1, ; US 5347013 A

288-42-6

145214-05-7

文献：WO2004/788 A1, ; Page 40 ; WO 2004/000788 A1

上游产品 2
288-42-6 1461-22-9
下游产品 3
769921-95-1 769922-03-4 62882-10-4

海关编码	2934999090
中文概述	2934999090. 其他杂环化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%
申报要素	品名, 成分含量, 用途
Summary	2934999090. other heterocyclic compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

145214-05-7	56280-67-2
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153435-63-3	332133-92-3
124252-41-1	173978-98-8
611168-46-8	105494-69-7