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148630-66-4生产厂家

148630-66-4价格

148630-66-4

148630-66-4结构式
148630-66-4结构式

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中文名 三甲基膦(六氟乙酰丙酮)银(I)
英文名 Trimethylphosphine(hexafluoroacetylacetonato)silver(I), 99% (99.9%-Ag)
沸点 95ºC 0,1mm
熔点 140-142ºC
分子式 C8H10AgF6O2P
分子量 390.99600
精确质量 389.93700
PSA 39.89000
LogP 3.40260
储存条件

密闭于阴凉干燥环境中

稳定性

遵照规定使用和储存则不会分解。

分子结构

1、摩尔折射率:无可用

2、 摩尔体积(cm3/mol):无可用

3、 等张比容(90.2K):无可用

4、 表面张力(dyne/cm):无可用

5、 极化率:无可用

更多

1. 性状:无可用

2. 密度(g/mL,25/4℃):无可用

3. 相对蒸汽密度(g/mL,空气=1):无可用

4. 熔点(ºC):140-142

5. 沸点(ºC,常压):95

6. 沸点(ºC,5.2kPa):无可用

7. 折射率:无可用

8. 闪点(ºC):无可用

9. 比旋光度(º):无可用

10. 自燃点或引燃温度(ºC):无可用

11. 蒸气压(kPa,25ºC):无可用

12. 饱和蒸气压(kPa,60ºC):无可用

13. 燃烧热(KJ/mol):无可用

14. 临界温度(ºC):无可用

15. 临界压力(KPa):无可用

16. 油水(辛醇/水)分配系数的对数值:无可用

17. 爆炸上限(%,V/V):无可用

18. 爆炸下限(%,V/V):无可用

19. 溶解性:无可用


Section 1: Product Identification
Chemical Name:Trimethylphosphine(hexafluoroaetylacetonato)silver (I), 99% (99.9%-Ag)
CAS Registry Number:148630-66-4
Formula:Ag(CF3COCHCOCF3)P(CH3)3
EINECS Number:None
Chemical Family:metal fluorobeta-diketonate complexes
Synonym:Trimethylphosphinesilver (I) hexafluoroacetylacetonate

Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title Compound148630-66-4100%0.01mg/m3 (Ag sl)0.01mg/m3 (Ag sl)

Section 3: Hazards Identification
Irritating to eyes, skin and respiratory tract. If inhaled or swallowed this compound may cause fluoride
Emergency Overview:
poisoning. Early symptoms include nausea, vomiting, diarrhea, and weakness
Primary Routes of Exposure:Ingestion, inhalation, skin, eyes
Eye Contact:Causes mild to severe irritation of the eyes
Causes slight to mild irritation of the skin. Contact with the skin can lead to formation of dark blotches (silver
Skin Contact:
staining)
Irritating to the nose, mucous membranes and respiratory tract. Inhalation Dust may cause fluoride poisoning.
Inhalation:
Ingestion may lead to dizziness, abdominal cramps, vomiting, bloody diarrhea, weakness, convulsions, and
Ingestion:
fluoride poisoning.
Irritating to skin, eyes and respiratory tract. Ingestion may lead to dizziness, abdominal cramps, vomiting,
Acute Health Affects:
bloody diarrhea, weakness, and convulsions.
Long term exposure to silver and silver salts can lead to the condition known as argyria - a general gray
Chronic Health Affects:pigmentation of the skin and mucous membranes. Chronic fluoride poisoning can cause severe bone
changes, loss of weight, and dental defects.
NTP:No
IARC:No
OSHA:No

SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
Flash Point:not applicable
Autoignition Temperature:none
Explosion Limits:none
Extinguishing Medium:none required
If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
Special Fire Fighting Procedures:
self- contained breathing apparatus and full protective clothing.
Hazardous Combustion andIf involved in a fire this material may emit toxic fumes.
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
To avoid raising dust, small spills may be mixed with diatomaceous earth, sand, vermiculite, or other suitable
Spill and Leak Procedures:
inert material and swept up.

SECTION 7: Handling and Storage
Handling and Storage:Store in a cool, dry place in a tightly sealed container.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear protective clothing and gloves.
Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood.
If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
Respirator:
Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood.
Additional Protection:No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:white to yellow xtl.
Molecular Weight:391
Melting Point:140-142°C
Boiling Point:subl. 95°C/0.1mm
Vapor Pressure:no data
Specific Gravity:no data
Odor:none
Solubility in Water:slightly soluble

SECTION 10: Stability and Reactivity
Stability:air and moisture stable
Hazardous Polymerization:no hazardous polymerization
Conditions to Avoid:none
Incompatibility:mineral acids, oxidizing agents and active metals
Decomposition Products:carbon monoxide, carbon dioxide, organic fumes, and silver salts.

SECTION 11: Toxicological Information
RTECS Data:No information available in the RTECS files.
Carcinogenic Effects:No data
Mutagenic Effects:No data
Tetratogenic Effects:No data

SECTION 12: Ecological Information
Ecological Information:No information available

SECTION 13: Disposal Considerations
Disposal:Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
Shipping Name (CFR):Non-hazardous
Hazard Class (CFR):NA
Additional Hazard Class (CFR):NA
Packaging Group (CFR):NA
UN ID Number (CFR):NA
Shipping Name (IATA):Non-hazardous
Hazard Class (IATA):NA
Additional Hazard Class (IATA):NA
Packaging Group (IATA):NA
UN ID Number (IATA):NA

SECTION 15: Regulatory Information
TSCA:Not listed in the TSCA inventory.
SARA (Title 313):Title compound: See category N740 for reporting.
Second Ingredient:None


SECTION 16 - ADDITIONAL INFORMATION
N/A

生态学数据:

该物质对环境可能有危害,对水体应给予特别注意。

风险声明 (欧洲) 20/21/22-36/37/38
安全声明 (欧洲) 26-36/37/39